Electrolyte dehydrohalogenation of .alpha.-haloalcohols

Details Electrolyte dehydrohalogenation of .alpha.-haloalcohols Electrolyte dehydrohalogenation of .alpha.-haloalcohols

1976-11-29

1978-07-04

Edmundson, F.C.

Chemistry: electrical and wave energy

Processes and products

204 72, 568845, 260654D, C25B 300, C07C 1700, C07C 2106, C07C 2900

Patent

active

040986578

ABSTRACT:
Reductive dehydrohalogenation of an .alpha.-haloalcohol to form an alkene by subjecting the haloalcohol to electrolysis in the presence of a liquid diluent and a strong mineral acid. The electrolysis may be carried out in a diaphragm cell using a high hydrogen over voltage cathode.

REFERENCES:
patent: 1901316 (1933-03-01), Meerwein
patent: 2552980 (1951-05-01), Ladd et al.
patent: 3324187 (1967-06-01), Litt et al.
patent: 4018838 (1977-04-01), Cleare
Abstract 762,873 by Ehrenfeld, Pub. 5/22/51.
Handbook of Chemistry & Physics, 52nd Ed., 1971, p. D-121, Pub. by Chemical Rubber Co.

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