Electrolysis of alkali metal chloride in a cell having a nickel-

Chemistry: electrical and wave energy – Processes and products

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204128, 204290R, 204293, C25B 134, C25B 1104

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active

042486793

ABSTRACT:
Disclosed herein is a cathode having an electroconductive substrate and a porous surface. The porous surface is characterized by containing a major portion of nickel and a hydrogen overvoltage reducing amount of molybdenum. The molybdenum may be present as elemental molybdenum, as an alloy with nickel, or as a molybdenum compound. Also disclosed is an electrolytic cell having an anode, a cathode, and a separator between the anode and cathode, where the cathode is characterized by a porous surface having a major portion of nickel and a hydrogen over voltage reducing amount of molybdenum, which molybdenum may be present as elemental molybdenum, and molybdenum alloy with nickel or a molybdenum compound.
Further disclosed is a method of electrolyzing an alkali metal chloride brine by passing an electrical current from an anode to a cathode to evolve chlorine at the anode and hydroxyl ion at the cathode. The cathode is characterized by a porous surface containing a major portion of nickel and hydrogen overvoltage reducing amount of molybdenum.
Also disclosed is a method of preparing a porous nickel electrode by flame spraying nickel bearing particles, leachable constituent bearing particles and molybdenum bearing particles onto a metal substrate and leaching out the leachable constituent whereby to form the porous surface.

REFERENCES:
patent: 4024044 (1977-05-01), Brannan et al.
patent: 4033837 (1977-07-01), Kuo et al.
patent: 4049841 (1977-09-01), Coker et al.
patent: 4080278 (1978-03-01), Ravier et al.
patent: 4170536 (1979-10-01), Kawasaki et al.
Modern Electroplating, F. A. Lowenheim, 2nd Ed., 1963, p. 649.

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