Electrodeposited doped II-VI semiconductor films and devices inc

Batteries: thermoelectric and photoelectric – Photoelectric – Cells

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136264, 136265, 357 16, 357 30, 357 61, 357 63, H01L 3106

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active

049098578

ABSTRACT:
A method of electrodepositing a doped compound semiconductor film including tellurium and a metal selected from Group IIB of the Period Table of Elements by adding an effective concentration of dopant ions to the electrolyte bath. Cadmium telluride, mercury cadmium telluride and zinc cadmium telluride may be doped with copper, silver and gold. The conductivity type of the electrodeposited doped layers may be changed by a heat treatment. Thin film photovoltaic cells incorporating the doped layer to form a heterojunction with a semiconductor layer of the opposite conductivity type show substantial improvements in open circuit voltage, fill factor and efficiency over similar devices employing undoped electrodeposited layers.

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