Electrodeless heterogeneous polypyrrole composite

Stock material or miscellaneous articles – Composite – Of addition polymer from unsaturated monomers

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252500, 252518, 252519, B32B 2708, H01B 106

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active

046802363

ABSTRACT:
A conductive composite is formed which consists of a host polymer and polypyrrole ("PP") deposited on and within the host polymer. Instead of using a conductor as a starting substrate, an insulating polymer is at least partially impregnated with sufficient pyrrole (PY) monomer to become conductive after the PY is polymerized. The polymerization is a chemical oxidative polymerization ("dip-polymerization") which, if carried out under anhydrous conditions, transforms the insulating polymer into a semiconductive composite consisting essentially of the host polymer containing a first species of conductive PP and a Group VIII metal halide counterion; thereafter, the semiconductive composite, containing the counterion, is used to electrodeposit on it a second species of conductive PP. The composite with the two species of PP and anions is used for EMI shielding, and in a host of applications where a lightweight organic resistance heating element is desired, for example in de-icers for the wings of an airplane, to melt snow on roof-tops and in gutters, and to warm a frigid seat in a vehicle.

REFERENCES:
patent: 4547270 (1985-10-01), Naarmann
patent: 4566955 (1986-01-01), Naarmann
patent: 4567250 (1986-01-01), Naarmann et al.
patent: 4568483 (1986-02-01), Naarmann et al.
patent: 4585581 (1986-04-01), Skotheim
patent: 4585695 (1986-04-01), Ogasawara et al.

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