Electrode containing thallium (III) oxide

Details Electrode containing thallium (III) oxide Electrode containing thallium (III) oxide

1983-08-18

1985-01-22

Niebling, John F.

Chemistry: electrical and wave energy

Apparatus

Electrolytic

204 56R, 204128, 204129, 204290R, 204290F, 4271263, C25F 100, C25B 1100

Patent

active

044950462

ABSTRACT:
An electrode useful in an electrolytic cell contains thallium (III) oxide. A method for enhancing the electrocatalytic activity and/or stability of an electrode includes compounding an outermost layer containing thallium (III) oxide with a conductive substrate. The electrode is particularly useful in reversible-type reactions such as the conversion of ferrocyanide to ferricyanide as well as in irreversible-type reactions, such as electrolysis of water to obtain hydrogen and oxygen or the electrolysis of chloride-containing solutions to obtain hydrogen and chlorine.

REFERENCES:
patent: 3632498 (1972-01-01), Beer
patent: 3711385 (1973-01-01), Beer
patent: 4028215 (1977-06-01), Lewis et al.
patent: 4040939 (1977-08-01), Schenker et al.
patent: 4065377 (1977-12-01), Zollner
patent: 4341612 (1982-07-01), Oda
patent: 4354915 (1982-10-01), Stachurski
Sharma, L. R. and Dutt, Jatinder, Indian Journal of Chemistry, vol. 8, pp. 170-173, (1970).
Ohzeki, K., Schunacher, E. and Umland, F., Fresenius Z. Anal. Chem., 293, pp. 18-22, (1978).
Kraft, G., Z. Anal. Chem., Bd. 238, pp. 321-414, (1967).

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