Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode
Reexamination Certificate
1998-05-19
2001-09-25
Ogden, Necholus (Department: 1751)
Chemistry: electrical current producing apparatus, product, and
Current producing cell, elements, subcombinations and...
Electrode
52
Reexamination Certificate
active
06294290
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to an electrode binder which is enhanced in its adhesion and high capacity characteristics. The present invention further relates to a method for manufacturing an active material slurry for a lithium-ion secondary battery, which contains the electrode binder.
2. Description of the Prior Art
Generally, a lithium-ion secondary battery is a rechargeable battery which is widely used in many applications.
The lithium-ion secondary battery uses a lithium transition metal oxide as a positive electrode and a carbon or graphite as a negative electrode. As an electrolyte, a compound solvent consisting of cyclic carbonates and linear carbonates, to which lithium hexafluoro phosphate (LiPF
6
) or lithium tetrafluoro boronate (LiBF
4
) as a supporting electrolyte is added, is used.
Accordingly, when the lithium-ion secondary battery is charged, lithium ions deintercalated from the positive electrode are inserted to the carbon or graphite of the negative electrode. During discharge of the lithium-ion secondary battery, lithium ions deintercalated from the carbon or graphite are inserted to the lithium transition metal oxide of the positive electrode.
The positive and negative electrodes applied with the active material are obtained by passing positive and negative substrates through a container containing an active material slurry, and drying and pressing the same.
The active material slurry consists of active material such as lithium transition metal oxide as the positive electrode and carbon or graphite as the negative electrode, a conducting agent and binder.
Polyvinylidene fluoride (PVDF) which is a fluoride polymer and is less reactive with the organic solvent which is used as the electrolyte is usually used as the binder. Alternatively, polyimide (PI) and rubber which are the polymer materials are also used as the binder.
The performance of the battery mostly depends on kinds of the active material used, and on the kinds of the binder contained in the active material slurry. For example, the cycle life, high capacity, and low temperature characteristic of a battery depend on the types of polymer of PVDF.
That is, if homopolymer of PVDF is used as the binder, required adhesion can be obtained, but it is difficult to coat the active material on the electrode substrate at a uniform thickness due to low liquidity of the active material slurry.
If copolymer of PVDF is used, it is easy to coat the active material on the electrode substrate and the high capacity of the battery can be obtained. However, since the electrolyte content rate becomes higher, the volume expansion of the battery is increased. This results in the active material being separated from the substrate.
SUMMARY OF THE INVENTION
The present invention has been made in an effort to solve the above described drawbacks of each prior binder.
It is an object of the present invention to provide a binder which is improved in its adhesion while providing high capacity characteristic.
It is another object of the present invention to provide a method for manufacturing an active material slurry using the inventive binder.
To achieve the above object, the present invention provides an electrode binder of a lithium-ion secondary battery. The binder comprises at least two materials selected from a polyvinylidene fluoride polymer.
The materials have the same chemical component as each other but different physical characteristic from each other.
According to an embodiment of the present invention, the materials comprise a homopolymer and a copolymer of PVDF . Preferably, a mixture ratio of the homopolymer and the copolymer are selected within a range of 50:50 to 95:5 wt %.
According to another aspect of the present invention, an electrode binder of a lithium ion secondary battery comprises at least two polymer materials which have a different chemical component from each other.
The materials comprise a polyvinylidene fluoride and a rubber polymer binder.
The rubber polymer binder is preferably selected from the group consisting of a styrene butadiene rubber and an ethylene propylene diene monomer(EPDM).
It is also preferable that the polyvinylidene fluoride and rubber polymer binder are mixed within a rate of 20:80 to 80:20 wt %.
According to still another aspect of the present invention, a method of forming an active material slurry used in a lithium-ion secondary battery, comprising the steps of mixing at least two materials selected from a polyvinylidene fluoride, chemical components of the materials being the same as each other and physical characteristic of the materials being different from each other, dissolving the mixture within an n-methyl pyrrolidone solvent, thereby obtaining a binder solution, and mixing an active material and a conducting agent with the binder solution.
According to yet another aspect of the present invention, a method of forming an active material slurry used in a lithium-ion secondary battery, comprising the steps of preparing a binding solution by mixing a rubber polymer binder with an n-methyl pyrrolidone solution containing a polyvinylidene fluoride; and mixing an active material and a conducting agent with the binding solution.
REFERENCES:
patent: 4302556 (1981-11-01), Endo et al.
patent: 5238739 (1993-08-01), Susa et al.
patent: 5589297 (1996-12-01), Koga et al.
patent: 5614334 (1997-03-01), Kamauchi et al.
patent: 5756230 (1998-05-01), Gao et al.
patent: 5783331 (1998-07-01), Inoue et al.
patent: 6019802 (2000-02-01), Ishizuka et al.
patent: 98/59387 (1998-12-01), None
Bushnell , Esq. Robert E.
Ogden Necholus
Samsung SDI & Co., Ltd.
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