Electrochemical process for the preparation of acetals of 2-halo

Chemistry: electrical and wave energy – Processes and products

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204 72, 204 78, 260615A, C25B 302, C07C 4110

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active

041207610

ABSTRACT:
Electrolysis of a substantially anhydrous electrolysis medium comprising a primary alcohol having at least one beta-hydrogen atom and anhydrous hydrogen halide selected from the group consisting of hydrogen chloride and hydrogen bromide yields acetals of 2-haloaldehydes corresponding to the primary alcohol.

REFERENCES:
patent: 3257298 (1966-06-01), Hughes
patent: 4046652 (1977-09-01), Pistorius et al.
Tomilov et al., J. Gen. Chem. USSR (trans Zh Obsh Khimii) vol. 44, No. 9, pt. 2 pp. 1990-1993 9-74.

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