Electrochemical process for producing chlorine dioxide solutions

Chemistry: electrical and wave energy – Processes and products

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204101, 204 95, 204129, 2041823, 2041824, 210638, 423477, C25B 126

Patent

active

050929704

ABSTRACT:
A process for electrolytically producing an aqueous solution of chlorine dioxide in an electrolytic cell having an anode compartment, a cathode compartment, and at least one ion exchange compartment between the anode compartment and the cathode compartment, the process comprising feeding an aqueous solution of an alkali metal chlorite to the ion exchange compartment, electrolyzing an anolyte in the anode compartment to generate hydrogen ions, passing the hydrogen ions from the anode compartment through a cation exchange membrane into the ion exchange compartment to displace alkali metal ions and produce an aqueous solution of chlorine dioxide, and passing alkali metal ions from the ion exchange compartment into the cathode compartment.

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