Electrochemical process for producing chloric acid - alkali meta

Chemistry: electrical and wave energy – Processes and products

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204 98, 204101, 204103, 2041823, 2041824, 423472, 423475, C25B 114, C25B 126

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050841483

ABSTRACT:
A process for electrolytically producing an aqueous solution of chloric acid and alkali metal chlorate in an electrolytic cell having an anode compartment, a cathode compartment, and at least one ion exchange compartment between the anode compartment and the cathode compartment. The process includes the steps of feeding an aqueous solution of an alkali metal chlorate to the ion exchange compartment, electrolyzing an anolyte in the anode compartment to generate hydrogen ions, passing the hydrogen ions from the anode compartment through a cation exchange membrane into the ion exchange compartment to displace alkali metal ions and produce an aqueous solution of chloric acid and alkali metal chlorate, and passing alkali metal ions from the ion exchange compartment into the cathode compartment.

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patent: 4798715 (1989-01-01), Hardee et al.
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patent: 4915927 (1990-04-01), Lipsztajn et al.
Ullmann's Encyclopedia of Industrial Chemistry, vol. A6, p. 497 (1986).

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