Electrochemical oxidation of pyridine bases

Chemistry: electrical and wave energy – Processes and products

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C25B 302

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044824394

ABSTRACT:
Improved electrochemical oxidations of alkylpyridine bases in which the oxidation is performed by electrolysis in a membrane divided flow cell at a lead dioxide anode and in an aqueous medium comprising sulfuric acid in at least a 1:1 equivalent ratio with the alkylpyridine base in solution. Significant advantages of a commercial and industrial nature are reported over prior static, beaker cell technology.

REFERENCES:
Fichter, Helv. Chim. Acta. 19 1171 (1936).
Yokoyama Bull. Chem. Soc. Jpn. 7 103 (1932).
Sagae, Heterocycles 13 321 (1979).

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