Electrochemical method, apparatus and carbon product

Electrolysis: processes – compositions used therein – and methods – Electrolytic synthesis – Utilizing fused bath

Reexamination Certificate

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Reexamination Certificate

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08057658

ABSTRACT:
In an electrolytic method for producing nano-scale carbon products, such as carbon nanotubes, first and second graphite electrodes contact a fused-salt electrolyte. A power supply is coupled to the electrodes and first and second voltages are alternately applied to the electrodes. The first voltage is applied such that the first electrode is at a cathodic potential relative to the second electrode, and the second voltage is applied such that the second electrode is at a cathodic potential relative to the first electrode. The method thus advantageously converts the carbon of both electrodes to nano-scale carbon products.

REFERENCES:
patent: 1378975 (2002-11-01), None
patent: 1579932 (2005-02-01), None
Dimitrov et al., “A Feasibility Study of Scaling-Up the Electrolytic Production of Carbon Nanotubes in Molten Salts”, Electrochimica Acta (no month, 2002), vol. 48, pp. 91-102.
Xu et al., “Electrochemical Investigation of Lithium Intercalation into Graphite from Molten Lithium Chloride”, J. of Electroanal. Chem. (no month, 2002), vol. 530, pp. 16-22.
Bai et al., “Synthesis of SWNTs and MWNTs by Molten Salt (NaCl) Method”, Chem. Phys. Lett. (no month, 2002), vol. 365, pp. 184-188.
Q. Xu et al., “Electromechanical Investigation of Lithium Intercalation into Graphite from Molten Lithium Chloride”, J. Elcctroanal. Chem., vol. 530, 2002, pp. 16-22.
Dimitrov A. et al., “A feasibility Study of Scaling-Up the Electrolytic Production of Carbon Nanotubes in Molten Salts”, Electrochimica ACTA, Elsevier Science Publishers, Barking, GB, vol. 48, No. 1, Nov. 4, 2002, pp. 91-102.
Kinloch I A et al., “Electrolytic, TEM and Raman Studies on the Production of Carbon Nanotubes in Molten NaCl”, Carbon, vo. 41, No. 6, 2003 pp. 1127-1141.

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