Electrochemical devices utilizing molten alkali metal electrode-

Chemistry: electrical current producing apparatus – product – and – Fluid active material or two-fluid electrolyte combination... – Active material in molten state

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429191, H01M 436

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active

046095969

ABSTRACT:
Electrochemical cells are provided with a reactive metal to reduce the oxide of the alkali metal electrode-reactant. Cells employing a molten alkali metal electrode, e.g., sodium, in contact with a ceramic electrolyte, which is a conductor of the ions of the alkali metal forming the electrode, exhibit a lower resistance when a reactive metal, e.g., vanadium, is allowed to react with and reduce the alkali metal oxide. Such cells exhibit less degradation of the electrolyte and of the glass seals often used to joining the electrolyte to the other components of the cell under cycling conditions.

REFERENCES:
patent: 4356241 (1982-10-01), Wright et al.
patent: 4407912 (1983-10-01), Virkar et al.
patent: 4430393 (1984-02-01), Bennett et al.

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