Electrochemical cells having solid electrolyte of tubular form

Chemistry: electrical current producing apparatus – product – and – Fluid active material or two-fluid electrolyte combination... – Active material in molten state

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429122, H01M 1039

Patent

active

040557103

ABSTRACT:
In an electrochemical cell, such as a sodium-sulphur cell, having a tube of solid electrolyte material separating a liquid alkali metal from a cathodic reactant, the electrolyte tube is surrounded by constraining means which apply an inward pressure as the cell temperature rises. This is achieved either by having a suitable means, e.g., wire, around the tube with a lower coefficient of expansion than the tube, or by putting powder or particles or corrugated metal or other constraining means between the tube and a surrounding housing, the materials being chosen to have appropriate coefficients of expansion to give the required inward pressure.

REFERENCES:
patent: 3413150 (1968-11-01), Kummer et al.
patent: 3841912 (1974-10-01), Kagawa et al.

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