Chemistry: electrical current producing apparatus – product – and – Fluid active material or two-fluid electrolyte combination... – Active material in molten state
Patent
1980-03-31
1981-11-24
Lefevour, Charles F.
Chemistry: electrical current producing apparatus, product, and
Fluid active material or two-fluid electrolyte combination...
Active material in molten state
429191, 429194, 423594, H01M 436
Patent
active
043025188
ABSTRACT:
There is interest in the use of solid-solution electrodes as a way of meeting the problems of conventional batteries; Li.sub.a TiS.sub.2 where O<a<1 is known in this respect and may be made by high temperature preparative routes.
Fast ion conductors of the formula A.sub.x M.sub.y O.sub.2 where A is Li, Na or K, M is a transition metal e.g. Co or Ni, <x<1 and y.apprxeq.1 have been made for this purpose according to the invention. They cannot be made by high temperature routes when x is substantially less than 1 owing to stability problems. In the invention, they have been made by electrochemical extraction of A.sup.+ ions from compounds of the formula A.sub.x' M.sub.y O.sub.2 where O<x'<1, carried out at low temperature.
REFERENCES:
patent: 3873369 (1975-03-01), Kamenski
patent: 3970473 (1976-07-01), Roth et al.
patent: 4198476 (1980-04-01), Di Salso, Jr. et al.
Goodenough John B.
Mizuchima Koichi
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