Electrochemical cell comprising stable hydride-forming material

Chemistry: electrical current producing apparatus – product – and – With pressure equalizing means for liquid immersion operation

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429 40, 429218, H01M 400

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active

044878176

ABSTRACT:
An electrochemical cell having a negative electrode comprising a compound derived from LaNi.sub.5, in which La is optionally substituted by a plateau pressure-increasing element and in which Ni is substituted entirely or partly by a plateau pressure-reducing element, for example, Co and/or Cu, with the object of considerably reducing volume steps and hence crack formation of the intermetallic compound during charging and discharging.
Moreover, the corrosion of the intermetallic compound is counteracted by adding small quantities of Al, Cr and/or Si, which metals enhance the formation of a protecting oxide layer.

REFERENCES:
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patent: 3850694 (1974-11-01), Dunlop et al.
patent: 3980501 (1976-09-01), Feder et al.
patent: 4112199 (1978-09-01), Dunlop et al.
patent: 4214043 (1980-07-01), Deutekom
patent: 4312928 (1982-01-01), Deutekom

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