Chemistry: electrical current producing apparatus – product – and – With pressure equalizing means for liquid immersion operation
Patent
1984-03-09
1984-12-11
LeFevour, Charles F.
Chemistry: electrical current producing apparatus, product, and
With pressure equalizing means for liquid immersion operation
429 40, 429218, H01M 400
Patent
active
044878176
ABSTRACT:
An electrochemical cell having a negative electrode comprising a compound derived from LaNi.sub.5, in which La is optionally substituted by a plateau pressure-increasing element and in which Ni is substituted entirely or partly by a plateau pressure-reducing element, for example, Co and/or Cu, with the object of considerably reducing volume steps and hence crack formation of the intermetallic compound during charging and discharging.
Moreover, the corrosion of the intermetallic compound is counteracted by adding small quantities of Al, Cr and/or Si, which metals enhance the formation of a protecting oxide layer.
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patent: 3980501 (1976-09-01), Feder et al.
patent: 4112199 (1978-09-01), Dunlop et al.
patent: 4214043 (1980-07-01), Deutekom
patent: 4312928 (1982-01-01), Deutekom
Buschow Kurt H. J.
Van Beek Johann R. G. C. M.
Willems Johannes J. G. S. A.
LeFevour Charles F.
Spain Norman N.
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