Electrochemical cell

Chemistry: electrical current producing apparatus – product – and – Fluid active material or two-fluid electrolyte combination... – Active material in molten state

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429112, H01M 1039

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active

045460558

ABSTRACT:
An electrochemical cell is provided with a molten sodium anode and a molten sodium aluminium halide salt electrolyte. The cathode comprises FeCl.sub.2, NiCl.sub.2, CoCl.sub.2 or CrCl.sub.2 as active cathode substance dispersed in an electronically conductive electrolyte-permeable matrix which is impregnated by the electrolyte. Between the anode and the electrolyte, and isolating them from each other, is a solid conductor of sodium ions or a micromolecular sieve which contains sodium sorbed therein. The proportions of sodium and aluminium ions in the electrolyte are selected so that the solubility of the active cathode substance in the electrolyte is at or near its minimum.

REFERENCES:
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patent: 4287271 (1981-09-01), Coetzer
patent: 4288506 (1981-09-01), Coetzer
Fung, Mamantov, Electrochemistry of Titanium(II) in AlCl.sub.3 +NaCl Melts, 35 J. Electroanal. Chem. 27 (1972).
Oye, Gruen, Cobalt(ii) Species in Fused Chloride Solvents 4(8) Inorg. Chem. 1173 (1965).
Boxall, Jones, Osteryoung, Electrochemical Studes in Ag, Fe, & Cu Species in AlCl.sub.3 -NaCl Melts, J. Electrochem. Soc. 212 (1974).
Gilbert, Osteryoung, Electrochemistry of Ni(II) & the Behav. of Oxide Ions in Chloroaluminate Melts, J. Amer. Soc. 2725 (Apr. 1978).
Miller, Exploring the Cell: Sodium/.beta.-Alumina/Cupric Between 136.degree. and 200.degree. C., Nasa Technical Mem. Nasa TMS-3245 (1975).
Chreitzberg, Consolloy, Manning, Sklarchuk, Performance of Molten Salt Sodium/.beta.-Alumina/SbCl3 Cells, 3 J. of Power Sources 201 (1978).

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