Electrochemical assay for cis-diols

Chemistry: molecular biology and microbiology – Measuring or testing process involving enzymes or... – Involving glucose or galactose

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435 4, 435 15, 435817, 435 25, 436 67, 2605023, 556 7, C12Q 154, C12Q 148, G01N 3372, C07F 902

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active

048206369

ABSTRACT:
The invention disclosed relates to an electrochemical assay which is particularly concerned with an assay for the presence of, or amount of, glycosylated haemoglobin in a blood sample, but which extends to a general assay for detecting the presence of, monitoring the level of or determining the concentration of compounds containing cis-diol groups, such as glycols, nucleic acid components, sugars, polyols, catechols and glycosylated proteins.
When ferrocene boronic acid or a derivative thereof is present free in solution, it can act as a mediator for a wide range of oxido-reductases. However in the presence of, for example, sugars containing the cis-diol structure, the metallocene (such as ferrocene boronic acid) covalently binds to the sugar. When the ferrocene boronic acid is thus bound, it is essentially immobilized and its properties as a mediator and ability to diffuse will be markedly affected.

REFERENCES:
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patent: 4582806 (1986-04-01), Bowsher et al.
patent: 4659817 (1987-04-01), Gallop et al.
Middle et al., "Separation of Glycosylated Hemoglobins Using Immobilized Phenylboronic Acid," Chem. Abst. 99:172205f, 1983.
"Affi-Gel 601", catalog.
"GlyoTest Kits", Pierce Chemical Company, Rockford, Ill.
"Glyco Gel", Pierce Chemical Company, Rockford, Ill.

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