Electrochemical analysis apparatus employing single ion measurin

Chemistry: electrical and wave energy – Processes and products – Vacuum arc discharge coating

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G01N 2726

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active

041499492

ABSTRACT:
Apparatus for measuring CO.sub.2 in serum with a single pH sensor of the electrolyte flow-through type, the sensor including a gas-permeable membrane selectively passing CO.sub.2 into an electrolyte filled space adjacent a pH sensing electrode for reacting with the electrolyte to produce a pH change therein. The electrolyte space is connected by a conduit to an electrolyte reservoir for flowing fresh electrolyte to and through the electrolyte space prior to a sample measurement. A stainless steel metal electrode directly contacts the electrolyte of constant composition in the conduit upstream of the pH sensor to derive a reference potential thereat. The potential across the pH sensor and the stainless steel electrode is monitored, differentiated, and the maximum value of the differentiated signal measured to determine the CO.sub.2 concentration.

REFERENCES:
patent: 3857771 (1974-12-01), Sternberg
patent: 3869354 (1975-03-01), Montalvo

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