Electrochemical additions to alkenes

Details Electrochemical additions to alkenes Electrochemical additions to alkenes

1980-06-10

1981-12-08

Edmundson, F.

Chemistry: electrical and wave energy

Processes and products

204 78, C25B 302

Patent

active

043046428

ABSTRACT:
Organic compounds having vicinal functional groups, such as amidothioethers and esterthioethers, are prepared by electrochemically oxidizing an organic disulphide, an organic diselenide, a hexasubstituted organic disilane or a tetrasubstituted organic hydrazine in the presence of an alkene and an organic nucleophile.

REFERENCES:
patent: 3798262 (1974-03-01), Rambacher et al.
patent: 4011240 (1977-03-01), Mauvernay et al.
patent: 4127454 (1978-11-01), Torii et al.
patent: 4219393 (1980-08-01), Torii et al.
Krimer et al., Chem. Abs., vol. 78, Abstract 159,027w (1973).
Takeshita, Chem. Abs., vol. 83, Abstract 163850e (1975).

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