Electrocatalytic cathodes and method of preparation

Chemistry: electrical and wave energy – Apparatus – Electrolytic

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427125, 4272554, 4273837, 427436, C25B 1108, B05D 512

Patent

active

050663801

ABSTRACT:
Cathodes useful in electrolytic cells, such as a chlor-alkali cell, are disclosed which have a metallic-surfaced substrate coated with an electrocatalytic coating. The electrocatalytic coating includes palladium and at least one primary electrocatlaytic metal, such as a platinum group metal. The coating optionally includes at least one secondary electrocatalytic metal, such as nickel, cobalt, iron, copper, manganese, molybdenum, cadmium, chromium, tin and silicon. Also disclosed is a non-electrolytic reduction method for preparing the cathodes. The method provides a tightly adherent coating, improves electrocatalyst loading and reduces cathode production costs.

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W. J. Moore, Physical Chemistry, (Prentice Hall 1962), 3rd Ed., pp. 406-408.

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