Electroanalytical method and sensor for hydrogen determination

Chemistry: electrical and wave energy – Processes and products

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204415, G01N 2746

Patent

active

045632499

ABSTRACT:
A method of and a sensor for quantitative electroanalytical determination of elemental hydrogen in a fluid medium are disclosed. A membrane enclosed amperometric cell is used that has at least two electrodes in contact with an aqueous electrolyte to provide a reaction impedance of the cell; the electrolyte is separated from the fluid medium by a membrane that is permeable to elemental hydrogen but substantially impermeable to the electrolyte and provides a membrane impedance of the cell; the electrodes include an anodic hydrogen sensing electrode and a cathodic counter electrode; the sensing electrode has a polished surface consisting of a platinum metal; further, the membrane is selected such that the membrane impedance exceeds the reaction impedance sufficiently to provide for membrane-controlled operation of the cell.

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