Electroactive polymer, device made therefrom and method

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S259000, C526S260000, C526S329200, C526S347000

Reexamination Certificate

active

10814748

ABSTRACT:
Disclosed are polymers comprising 2-(7-benzothiazolyl-9,9-disubstituted fluorene) structural units of the formulawherein R1and R2are each independently an alkyl group, an aralkyl group, an aryl group, or an —Si(R)3group wherein R is an alkyl group; R3is selected from the group consisting of an electron-donating substituent and an electron-withdrawing substituent; x has the value of from zero up to the number of hydrogens available for substitution on the aromatic ring; Z and Q are each independently a group which is in conjugation with both the fluorene group and the benzothiazole group; and the parameters j and k each independently have the value of 0–2. Electroactive devices comprising said polymers, methods for preparing said polymers, and monomers for preparing said polymers are also disclosed.

REFERENCES:
patent: 2004/0234809 (2004-11-01), Chen et al.
Belfield et al. Polymeric Materials Science and Engineering (2001), 84, 660-661.
K.D. Belfield, et al, “Synthesis of New Two-Photon Absorbing Fluorene Derivatives via Cu-Mediated Ullmann Condensations”, J. Org. Chem., vol. 15(65), 4475 (2000).
R. Kannan, et al, “Diphenylaminofluorene-Based Two-Photon-Absorbing Chromophores with Various p-Electron Acceptors”, Chem. Mat., vol. 13, 1896 (2001).
S.M. Kirkpatrick, et al, “Holographic recording using two-photon-induced photopolymerization”, Appl. Phys. A, , vol. 69, 461 (1999).

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