Electro-optical devices from banana-shaped liquid crystals

Stock material or miscellaneous articles – Liquid crystal optical display having layer of specified...

Reexamination Certificate

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C252S299010, C349S168000, C349S172000, C349S174000

Reexamination Certificate

active

06924009

ABSTRACT:
A liquid crystal device comprising tilted smectic phases of banana-shaped liquid crystal molecules is disclosed. A method for fabricating a light modulating device is also disclosed. The method comprises the steps of providing a pair of substrates with a cell gap therebetween and permanently disposing at least one banana-shaped liquid crystal material into said cell gap. The present invention also provides a method of generating an image, comprising providing a pair of substrates with a cell gap therebetween, providing transparent electrodes on each of the substrates adjacent to the cell gap, disposing at least one banana-shaped liquid crystal material into the cell gap; and applying an electric field across the electrodes. The tilted smectic phases of banana-shaped liquid crystal may be in either a racemic or a chiral state. The application of a sufficiently high electric field transitions the banana-shaped liquid crystal material between the racemic and chiral states, and both the racemic and the chiral states are stable in the absence of an electric field.

REFERENCES:
patent: 6130739 (2000-10-01), Shimoshikiryo et al.
patent: XP-002209488 (2000-04-01), None
patent: 2001303058 (2001-10-01), None
English translation by computer for JP 2001-303058, http://www4.ipdl.ncipi.go.jp/Tokujitu/PAJdetail.ipdl?N0000=60&N0120=01&N2001=2&N3001=2001-303058.
CAPLUS 2003:355372.
Tomoko Sekine, T. Niori, J. Watanabe, T. Furukawa, S.W.Choi, and H. Takezoe, “Spontaneous Helix Formation in Smectic Liquid Crystals Comprising Achiral Molecules”,J. Mater. Chem.,1997, 7(8), pp. 1307-1309.
Darren R. Link, Giorgio Natale, Renfan Shao, Joseph E. Maclennan, Noel A. Clark, Eva Körblova, and David M. Walba, “Spontaneous Formation of Macroscopic Chiral Domains in a Fluid Smectic Phase of Achiral Molecules”,Science,vol. 278, Dec. 12, 1997, pp. 1924-1927.
G. Pelzl, S. Diele, S. Grande, A. Jakli, Ch. Lischka, H. Kresse, H. Schmalfuss, I. Wirth and W. Weissflog, “Structural and Electro-Optical Investigations of the Smectic Phase of Chlorine-Substituted Banana-Shaped Compounds”,Journal of Liquid Crystals,vol. 26, No. 6, 1999, 401-413.
G. Heppke, A. Jakli, S. Rauch and H. Sawade, “Electric-Field-Induced Chiral Separation in Liquid Crystals”,Physical Review E,vol. 60, No. 5, Nov., 1999, pp. 5575-5579.
Gerhard Pelzl, Siegmar Diele, and Wolfgang Weissflog, “Banana-Shaped Compounds—A New Field of Liquid Crystals”,Advanced Materials,vol. 11, No. 9, 1999, pp 707-724.
Gerd Heppke and Dirk Moro, “Chiral Order from Achiral Molecules”,Science,vol. 279, Mar. 20, 1998, pp. 1872-1873.
A. Jakli, S. Rauch, D. Lötzsch, and G. Heppke, “Uniform Textures of Smectic Liquid-Crystal Phase Formed by Bent-Core Molecules”,Physical Review E,vol. 57, No. 6, Jun. 1998, pp. 6737-6740.

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