Electrically conductive, optically transparent...

Compositions – Electrically conductive or emissive compositions – Elemental carbon containing

Reexamination Certificate

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C252S500000, C252S511000, C423S447100, C423S447300, C423S44500R, C524S495000, C524S496000, C528S086000, C528S271000, C528S272000, C528S335000, C528S337000, C428S323000, C428S357000, C428S367000, C428S398000

Reexamination Certificate

active

07906043

ABSTRACT:
The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400-800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (Tg) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.

REFERENCES:
patent: 4810734 (1989-03-01), Kawasumi et al.
patent: 5357040 (1994-10-01), McGrath et al.
patent: 5466431 (1995-11-01), Dorfman et al.
patent: 5470910 (1995-11-01), Spanhel et al.
patent: 5554670 (1996-09-01), Giannelis et al.
patent: 5591382 (1997-01-01), Nahass et al.
patent: 5611964 (1997-03-01), Friend et al.
patent: 5638251 (1997-06-01), Goel et al.
patent: 5643502 (1997-07-01), Nahass et al.
patent: 5643990 (1997-07-01), Uehara et al.
patent: 5658653 (1997-08-01), Bosnyak et al.
patent: 5686585 (1997-11-01), Hishiro et al.
patent: 5786068 (1998-07-01), Dorfman et al.
patent: 5788738 (1998-08-01), Pirzada et al.
patent: 5840796 (1998-11-01), Badesha et al.
patent: 5851507 (1998-12-01), Pirzada et al.
patent: 5853877 (1998-12-01), Shibuta
patent: 5868966 (1999-02-01), Wei et al.
patent: 5876812 (1999-03-01), Frisk et al.
patent: 5877248 (1999-03-01), Beall et al.
patent: 5905000 (1999-05-01), Yadav et al.
patent: 5908585 (1999-06-01), Shibuta
patent: 5952040 (1999-09-01), Yadav et al.
patent: 5972448 (1999-10-01), Frisk et al.
patent: 6038060 (2000-03-01), Crowley
patent: 6057035 (2000-05-01), Singh et al.
patent: 6066269 (2000-05-01), Wei et al.
patent: 6136909 (2000-10-01), Liao et al.
patent: 6156835 (2000-12-01), Anderson et al.
patent: 6228904 (2001-05-01), Yadav et al.
patent: 6252020 (2001-06-01), Kuo et al.
patent: 6265466 (2001-07-01), Glatkowski et al.
patent: 6287992 (2001-09-01), Polansky et al.
patent: 6323270 (2001-11-01), Ishida
patent: 6348295 (2002-02-01), Griffith et al.
patent: 6361861 (2002-03-01), Gao et al.
patent: 6368569 (2002-04-01), Haddon et al.
patent: 6372837 (2002-04-01), Fischer et al.
patent: 6403231 (2002-06-01), Mueller et al.
patent: 6410142 (2002-06-01), Chen et al.
patent: 6419717 (2002-07-01), Moy et al.
patent: 6426134 (2002-07-01), Lavin et al.
patent: 6599961 (2003-07-01), Pienkowski et al.
patent: 7008563 (2006-03-01), Smalley et al.
patent: 7060241 (2006-06-01), Glatkowski
patent: 2002/0001620 (2002-01-01), Pienkowski et al.
patent: 2002/0048632 (2002-04-01), Smalley et al.
patent: 2002/0068170 (2002-06-01), Smalley et al.
patent: 2002/0161101 (2002-10-01), Carroll et al.
patent: 2002/0197474 (2002-12-01), Reynolds
patent: 2003/0089893 (2003-05-01), Niu et al.
patent: 2003/0158323 (2003-08-01), Connell et al.
patent: 1329111 (2002-01-01), None
patent: 1 054 036 (2000-11-01), None
patent: 2000-026760 (2000-01-01), None
patent: 2001-011344 (2001-01-01), None
patent: 2003-003047 (2003-01-01), None
Qiu et al, “Conducting Polyaniline Nanotubes by Template-Free Polymerization,” Macromolecules, 2001,34, 675-677.
Yong K. Kim, A.F. Lewis, S.B. Warner, P.K. Patra, & P. Calvert, “Nanocomposite Fibers,” National Textile Center Annual Report, p. 1-10, 2003.
Q.H. Wang, T.D. Corrigan, J.Y. Dal, R.P.H. Chang, & A.R. Krauss, “Field Emission from Nanotube Bundle Emitters at Low Fields,” Appl. Phys. Lett, American Institute of Physics, vol. 70 ( No. 24), p. 3308-3310, ( Jun. 16, 1997).
E.T. Mickelson, I.W. Chiang, J.L. Zimmerman, P.J. Boul, J. Lozano, J. Liu, R.E. Smalley, R.H. Hauge, & J.L. Margrave, “Solvation of Fluorinated Single-Wall Carbon Nanotubes in Alcohol Solvents,” J. Phys. Chem, American Chemical Society, p. 4318-4322, ( May 3, 1999).
Xiaoyi Gong, Jun Liu, Suresh Baskaran, Roger D. Voise, & James S. Young, “Surfactant-Assisted Processing of Carbon Nanotube/Polymer Composites,” Chem Master, 2nd ed., American Chemical Society, p. 1049-1052, ( Mar. 17, 2000).
J. N. Coleman, S. Curran, A.B. Dalton, A.P. Davey, B. McCarthy, W. Blau, & R.C. Barklie, “Percolation-Dominated Conductivity in a Conjugated-Polymer-Carbon-Nanotube Composite,” Rapid Communications, The American Physical Society, p. 7492-7495, ( May 19, 1998).
A.B. Kaiser, G. Dusberg, & S. Roth, “Heterogeneous Model for Conduction in Carbon Nanotubes,” Physical Review, The American Physical Society, p. 1418-1421, ( Aug. 22, 1997).
Seamus A. Curran, Pulicket M. Ajayan, Werner J. Blau, David L. Carroll, Johnathan N. Coleman, Alan B. Dalton, Andrew P. Davey, Anna Drury, Brendan McCarthy, Stephanie Maier, & Adam Stevens, “A Composite from Poly(m-phenylenevinylene-co-2,5-dioctoxy-p-phenylenevinylene) and Carbon Nanotubes: A Novel Material for Molecular Optoelectronics,” Advanced Materials, Weinheim, p. 1091-1093, ( Oct. 31, 1998).
Milo S.P. Shaffer & Alan H. Windle, “Fabrication and Characterization of Carbon Nanotube/Poly(vinyl alcohol) Composites,” Advanced Materials, Weinheim, p. 937-941. ( Oct. 31, 1999).
J. Sandler, M.S.P. Shaffer, T. Prasse, W. Bauhofer, K. Schulte, & A.H. Windle, “Development of a Dispersion Process for Carbon Nanotubes in an Epoxy Matrix and the Resulting Electrical Properties,” Polymer Communication, Elsevier Science Ltd., p. 5967-5971, ( Oct. 31, 1999).
R. Haggenmueller, H.H. Gommans, A.G. Rinzler, J.E. Fischer, & K.I. Winey, “Aligned Single-Wall Carbon Nanotubes in Composites by Melt Processing Methods,” Chemical Physics Letters, Elsevier Science, p. 219-225, ( Oct. 31, 2000).
Zhijie Jia, Zhengyuan Wang, Cailu Xu, Ji Liang, Bingqing Wei, Dehai Wu, Shaowen Zhu, “Study on Poly(methyl methacrylate)/Carbon Nanotube Composites,” Materials Science & Engineering, Elsevier Sciences, p. 395-400, ( Oct. 31, 1999).
Junhua Fan, Meixang Wan, Daoben Zhu, Baohe Chang, Zhenwei Pan, & Sishen Xie, “Synthesis, Characterizations, and Physical Properties of Carbon Nanotubes Coated by Conducting Polypyrrole,” Journal of Applied Polymer Sciences, John Wiley & Sons, Inc., p., 1999.
Cheol Park, Zoubeida Ounaies, Kent A. Watson, Kristin Pawlowski, Sharon E. Lowther, John W. Connell, Emilie J. Siochi, Joycelyn S. Harrison, & Terry L. St. Clair, “Polymer-Single Wall Carbon Nanotube Composite for Potential Spacecraft Applications,” Nov. 26-30, 2001.
Peter T. Lillehei, Cheol Park, Jason H. Rouse, & Emilie J. Siochi, “Imaging Carbon Nanotubes in High Performance Polymer Composite via Magnetic Force Microscopy,” Nano Letters, American Chemical Society, vol. 2 (No. 8), p. 827-829, (Apr. 17, 2002).
Cheol Park, Zoubeida Ounaies, Kent A. Watson, Roy E. Crooks, Joseph Smith, Jr., Sharon E. Lowther, John W. Connell, Emilie J. Siochi, Joycelyn S. Harrison & Terry L. St. Clair, “Dispersion of Single Wall Carbon Nanotubes by in Situ Polymerization Under Sonication,” Chemical Physics Letters, 2002.
Sumio Lijima, “Helical Microtubules of Graphitic Carbon,”Letters to Nature, Nature, p. 56-58, (Nov. 7, 1991).
P.M. Ajayan, “Nanotubes from Carbon, ”Chem Rev., American Chemical Society, p. 1787-1799, (Jun. 29, 1998).
Andreas Thess, Roland Lee, Pavel Nikolaev, Hongjie Dai, Pierre Petit, Jerome Robert, Chunhui Xu, Young Hee Lee, Seong Gon Kim, Andrew G. Rinzler, Daniel T. Colbert, Gustavo Scuseria, David Tomanek. John E. Fischer, & Richard E. Smalley, Crystalline Ropes of Metallic, Science, 1996.
Stanislaus S. Won

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