Electrically conductive composites and method of preparation

Chemistry: electrical and wave energy – Processes and products

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204 3, 204 20, 204 21, 204 22, 204 56R, 204 59R, 204 72, 528423, 548564, C25D 100, C25D 902

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active

045825750

ABSTRACT:
Electrically conductive composites comprising a dielectric porous substance, e.g. fiberglass fabric, and a pyrrole polymer deposited in the pores of such substance. The composites are produced by contacting the porous substance with an anode in an electrolytic cell containing an electrolyte comprising a pyrrole monomer and a substantially non-nucleophilic anion such as bisulfate, and passing an electric current through the cell, thus electrochemically precipitating a conductive pyrrole polymer in the pores of such substance.

REFERENCES:
patent: 2354110 (1944-07-01), Ford et al.
patent: 2734004 (1956-02-01), Robinson
patent: 4214031 (1980-07-01), Miyakawa et al.
patent: 4401545 (1983-08-01), Naarmann et al.
patent: 4468291 (1984-08-01), Naarmann et al.
patent: 4487667 (1984-12-01), Traynor
patent: 4488943 (1984-12-01), Skotheim
"Electrochemical Polymerization of Pyrrole on Polymer-Coated Electrodes" by O. Niwa and T. Tamamura, J. Chem. Soc., Chem. Commun., Jul. 1, 1984 issue, pp. 817 and 818.

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