Chemistry of inorganic compounds – Rare earth compound
Patent
1994-07-29
1996-06-04
Jordan, Charles T.
Chemistry of inorganic compounds
Rare earth compound
C01F 1700
Patent
active
H00015407
ABSTRACT:
Mixed metal chalcogenides formed of lanthanide chalcogenides having the formula MLnX.sub.2 where M is selected from the group consisting of Ag, Cu and Au; Ln is one of the elements of the lanthanide family other than Pm and X is selected from the group consisting of S, Se and Te and having electrical properties that range from dielectrics to semiconductors to metallic conductors in a temperature range from -50.degree. C. to in excess of +100.degree. C. The lanthanide chalcogenides can be prepared by slow fusion of the basic elements such as silver, lanthanum and selenium, in substantially stoichiometric properties, in powder form under an extended time period at elevated temperature, e.g. 650.degree. C. to 700.degree. C.
REFERENCES:
patent: 2814004 (1957-10-01), Goodman
patent: 4061505 (1977-12-01), Hampl, Jr.
"Rare Earth Copper Sulphides, CulnS.sub.2 " by T. Murugesan et al. Proc. l. Phys. Solid State Phys. Symp. 25 (c) English pp. 123-124 (1982).
"Rare Earth Copper Sulphides (LnCuS.sub.2)" by Murugesan et al.; Indian Journal of Chem. vol. 22A Jun. 1983 pp. 469-474.
"Chemical Principles" by Marterton et al.; 4th ed. pub. by W. B. Saunders Co. 1977 p. 153.
Chemical Abstract No. 105:182, 672n by Agaev et al.; Chem. Abstracts vol. 105 No. 20 17 Nov. 1986 p. 697.
Hardee John R.
Jordan Charles T.
Sliwka Melvin J.
The United States of America as represented by the Secretary of
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