Electrical components formed of lanthanide chalcogenides and met

Chemistry of inorganic compounds – Rare earth compound

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C01F 1700

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H00015407

ABSTRACT:
Mixed metal chalcogenides formed of lanthanide chalcogenides having the formula MLnX.sub.2 where M is selected from the group consisting of Ag, Cu and Au; Ln is one of the elements of the lanthanide family other than Pm and X is selected from the group consisting of S, Se and Te and having electrical properties that range from dielectrics to semiconductors to metallic conductors in a temperature range from -50.degree. C. to in excess of +100.degree. C. The lanthanide chalcogenides can be prepared by slow fusion of the basic elements such as silver, lanthanum and selenium, in substantially stoichiometric properties, in powder form under an extended time period at elevated temperature, e.g. 650.degree. C. to 700.degree. C.

REFERENCES:
patent: 2814004 (1957-10-01), Goodman
patent: 4061505 (1977-12-01), Hampl, Jr.
"Rare Earth Copper Sulphides, CulnS.sub.2 " by T. Murugesan et al. Proc. l. Phys. Solid State Phys. Symp. 25 (c) English pp. 123-124 (1982).
"Rare Earth Copper Sulphides (LnCuS.sub.2)" by Murugesan et al.; Indian Journal of Chem. vol. 22A Jun. 1983 pp. 469-474.
"Chemical Principles" by Marterton et al.; 4th ed. pub. by W. B. Saunders Co. 1977 p. 153.
Chemical Abstract No. 105:182, 672n by Agaev et al.; Chem. Abstracts vol. 105 No. 20 17 Nov. 1986 p. 697.

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