Elastomeric polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

Reexamination Certificate

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C528S015000, C528S019000, C528S033000, C525S477000, C556S431000

Reexamination Certificate

active

10718764

ABSTRACT:
Acyclic diene metathesis (ADMET) has been utilized in the synthesis of carbosilane and carbosiloxane polymers bearing a latent reactive methoxy-functional group on each repeat unit. The polymerization results in a linear thermoplastic polymer. The latent reactive methoxy groups remain inert during polymerization; however, exposure to moisture triggers hydrolysis and the formation of a chemically cross-linked thermoset. The thermoset's properties can be modified by varying the ratio of carbosilane and carbosiloxane repeat units in the final material. Also, increasing cross-link density by using cross-linkable chain-end groups and increasing the run length of the soft phase, maximizing phase separation and elasticity, allows for the synthesis of elastic thermosets exhibiting good tensile strength. Adding a trifunctional ADMET active chain-end cross-linker to the system improved the mechanical behavior of the resulting polymer.

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Brzezinska, et al., Journal of Polymer science, Part A: Polymer Chemistry, 38, (2000), 1544-1550.

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