Eerrocene derivatives, surfactants containing same and process f

Details Eerrocene derivatives, surfactants containing same and process f Eerrocene derivatives, surfactants containing same and process f

1991-05-09

1992-08-04

Niebling, John

Electrolysis: processes, compositions used therein, and methods

Electrolytic coating

Forming nonmetal coating

252351, 252353, 252357, 556143, 556144, C25D 902

Patent

active

051356376

ABSTRACT:
A process for producing an organic thin film, wherein a hydrophobic organic substance is admixed with a ferrocene compound in an aqueous medium to solubilize the hydrophobic organic substance and form a micelle solution. The micelle solution is electrolyzed to form thin film of the hydrophobic organic substance on an anode. The ferrocene compound has the formula: ##STR1## wherein R.sup.1 and R.sup.2 are identical or different and are a hydrogen, a methyl group, a methoxyl group, an amino group, a dimethylamino group, a hydroxyl group or halogen, X is ##STR2## M is an alkali metal or an alkaline earth metal, a is an integer of 1 to 4, b is an integer of 1 to 5, k is an integer of 1 to 18 and m is an integer of 0 to 4.

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R. P. Seiders et al, "Synethesis and reactivity of surfactant ferrocene. Environmental effects on oxidation of ferrocene in organized media." 1980, p. 670, Chemical Abstracts, 92:181326d.
K. Haage et al, "On surface-active ferrocene derivatives", 1987, Chemical Abstracts, vol. 107, abstract 200963f.

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