Durable wrinkle reduction laundry product compositions with...

Details Durable wrinkle reduction laundry product compositions with... Durable wrinkle reduction laundry product compositions with...

2000-11-06

2003-06-24

Gupta, Yogendra N. (Department: 1751)

Bleaching and dyeing; fluid treatment and chemical modification

Chemical modification of textiles or fibers or products thereof

Cellulose fibers

C008S137500, C510S285000

Reexamination Certificate

active

06582476

ABSTRACT:

FIELD
The present disclosure relates to laundry product compositions that provide a substrates, such as fabrics, with durable wrinkle reduction benefits and with improved softness. The composition can be used in both domestic and industrial processes.
BACKGROUND
Durable press treatments (a.k.a. “permanent” press treatments) in the textile industry are well known. In the 1960's, it was known to use polycarboxylic acids for permanent press treatment of textiles. Generally, cellulose fiber can be cross-linked and esterified with polycarboxylic acids, particularly those with two or more carboxylic acid groups. Esterification is achieved upon heating the treated cellulose fibers such as by ironing or other from of heat pressing. Curing catalysts, such as phosphorous containing salts, are also known and serve to aid cross-linking. The treated and cured textile is generally strengthened and is less likely to wrinkle during use. Examples of U.S. Patent relating to durable press finishing of cotton textile with polycarboxylic acids include: U.S. Pat. No. 4,820,307 (Welch et al.), U.S. Pat. No. 4,975,209 (Welch et al.) and U.S. Pat. No. 5,221,285 (Andrews et al.). The contents of these patents are incorporated by reference.
A disadvantage of known durable press treatments is that the treated and cured textile is typically less soft as compared to the uncured textile. In order to increase softness, inert nonionic or anionic materials have been proposed in formulations as fabric softeners. These softeners include polyethylene, polypropylene and silicone softeners. A disadvantage of these softeners is that they require an additional treatment step subsequent to the durable press treatment and are not durable.
Therefore, there is a need for durable press treatments that not only impart wrinkle reduction benefits but also impart softness benefits, i.e. durable softness. It would be preferable of the softness benefits could be achieved without additional steps subsequent to the durable press treatment.
SUMMARY
The present disclosure relates to durable wrinkle reduction products that impart durable softness. The products can be any substrate that have hydroxyl groups capable of forming cross-linked matrices. If the substrate is a fabric, the softness benefits are realised, for example, after machine or line drying.
In a preferred embodiment, silicone containing compounds are incorporated into the cross-linked matrix of cellulosic fibers of fabric. This is achieved by either 1) reacting the hydroxyl groups of the cellulosic fibers with polycarboxylic acids, wherein the polycarboxylic acids have silicone containing molecules and/or 2) by reacting other molecules having both hydroxyl groups and one or more silicones with the cross-linked polycarboxylic acid/cellulose matrix. It is believed that the incorporated silicone molecules will provide lubrication of the fiber surfaces, resulting in wrinkle reduction, softening and less abrasion on the fiber surface. A most preferred embodiment includes silicone carboxylates, however any silicone compound containing a hydroxy or silanol group or other functional group that can react with the cross-linked matrix can provide the desired affect. When cured, to form an ester, the silicone containing molecules are difficult to remove under normal wash and wear conditions.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Durable press treatment of cellulosic fibers is achieved by the esterification of cellulosic hydroxyl groups with polycarboxylic acids. The present disclosure of durable softness is achieved by including silicone carboxylates into the formulations. Silanols and hydroxy containing organically modified silicone fluids can be incorporated into the cross-linked matrix by reacting with (i.e. another esterification reaction) with the polycarboxylic acid.
Other molecules containing multiple hydroxyl groups, such as triethanol amine, can be incorporated into the cross-linked matrix. The silicone carboxylates could also react with these molecules.
The durable softness compounds are preferably selected form the following molecular classes: silicon carboxylates; silanol fluids; silanols and hydroxy containing organically modified silicone fluids. Most preferred compounds are carboxylic acid derivatized silicones that include any silicone with a —COOH group. These compounds are preferably incorporated into formulations useful for forming cross-linked matrices with cellulosic fibers. Preferred compounds for forming cross-linked matrices include, for example, 1,2,3,4 cyclopentanetetracarboxylic acid, 1,2,3,4 butanetetracarboxylic acid (BTCA) and polyacrylic acids. Other suitable carboxylic acids are disclosed in the above-cited patents and in U.S. Pat. No. 5,965,517 (Mooney), the contents of which are incorporated herein by reference.
A highly preferred composition in accordance with the present disclosure is Monosil® PCA (polysiloxyl pyrrolidone carboxylic acid, CAS number 179005-03-9) available from Mona Industries, Easley, S.C., which is included with BTCA to form the desired cross-linked matrix.


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International Search Report dated May 4, 2001 on PCT/EP 00/12536 Nov. 12, 2000.
Introduction of Ester Links into Cotton Cellulose by a Rapid Curing Process, Rowland et al., 1967, Textile Research Journal, pp. 933-941 Jun. 30, 1967.
Mobile Ester Cross Links for Thermal Creasing of Wrinkle-Resistant Cotton Fabrics, Rowland et al., Textile Research Journal, 1968, pp. 634-643 Oct. 23, 1967.

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