Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...
Reexamination Certificate
1999-04-14
2002-01-29
Cain, Edward J. (Department: 1714)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Processes of preparing a desired or intentional composition...
Reexamination Certificate
active
06342544
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to a durable outsole for an article of footwear. More particularly, the invention relates to a thermoplastic polyurethane outsole for an article of footwear having dispersed fluorocarbon additives, preferably perfluoropolyether (“PFPE”) additive, in the ground engaging portions of the outsole, such as a cleat of a cleated athletic shoe, thereby improving wear resistance and traction of the outsole.
BACKGROUND OF THE INVENTION
Modem articles of footwear, such as athletic shoes, are a highly refined combination of many elements which have specific functions, all of which work together for the support and protection of the foot. Athletic shoes today are as varied in design and purpose as are the rules for the sports in which the shoes are worn. Tennis shoes, racquetball shoes, basketball shoes, running shoes, soccer shoes, baseball shoes, football shoes, walking shoes, etc. are all designed to be used in very specific, and very different, ways. They are also designed to provide a unique and specific combination of traction, support and protection to enhance performance.
In general, an athletic shoe is divided into two general parts, an upper and a sole. The upper is designed to snugly and comfortably enclose the foot. Typically, it will have several layers including a weather and wear-resistant outer layer of leather or synthetic material, such as nylon, and a soft, padded inner layer for foot comfort.
The sole provides a broad, stable base to support the foot during ground contact. The sole must also provide traction, protection, and a durable wear surface. It must have an extremely durable bottom surface to contact the ground, together with a shock absorbing midsole to absorb the considerable force to which the foot and leg are subjected during the repeated ground contact which occurs during running. In addition, protruding traction members, or cleats, are desirable on the ground engaging portions of the bottom surface for certain sports such as baseball and soccer.
Cleats of soles are traditionally molded with natural materials, such as rubber, or synthetic materials, such as high abrasion thermoplastic polyurethanes (“TPU's”). TPU commonly used in such applications is sold by the Bayer Corporation under the trademarks TEXIN™ and DESMOPAN™. However, such cleats tend to become clogged with debris during use, and wear down with repeated use.
As explained more fully in U.S. Pat. No. 5,832,636 to Lyden et al, the disclosure of which is hereby incorporated by reference, one method for preventing cleats from becoming clogged during use is to include an adhesion prevention material having both a low coefficient of friction and a low wettability with respect to water in a portion of the ground engaging surface. Preferred adhesion prevention materials include using “neat polymers,” such as polytetrafluoroethylene (“PTFE”), compounded with “pigments, fillers, reinforcements, lubricants, processing aids, and curatives” to make useful compositions having a coefficient of friction preferably less than 0.4. In order to prevent a reduction in traction, the tips of the cleats in Lyden et al. remain substantially free of such adhesion prevention material.
U.S. Pat. Nos. 5,143,963 and 5,286,773 to Sterling, et al., the disclosures of which are hereby incorporated by reference, disclose a composition of matter formed by melt-blending a thermoplastic polymer with a concentration of fluorocarbon additive ranging between 0.01% to 1%. Disclosed fluorocarbon additives include perfluoropolyether (“PFPE”), such as KRYTOX™ manufactured and sold by the E. I. DuPont DeNemours Corporation. Sterling et al. discloses the tensile strength, surface energy, and water contact angles of the various compositions disclosed, and suggests that because of the high hydrophobicity and low surface energy, “sticking” of the composition to a mold during the molding process is reduced, thereby enhancing mold release. These references are silent regarding the durability of the compositions disclosed, and they neither teach nor suggest using such compositions in the ground engaging portions of an article of footwear for improved durability.
U.S. Pat. No. 5,864,968 to Mann, the disclosure of which is hereby incorporated by reference, discloses a shoe insole having a container containing liquid PFPE for absorbing the impact of a foot wearing the shoe. There is no teaching or suggestion in Mann to use or combine PFPE, or other disbursed fluorocarbon additives, with polymers to provide wear resistant ground engaging portions of the sole of a shoe.
Thus, despite the disclosures of the above-discussed patents, there remains a need for an article of footwear having a sole with durable ground engaging portions, particularly at the tips of any protruding traction members or cleats, without adversely affecting the traction of these ground engaging portions.
SUMMARY OF THE INVENTION
An article of footwear, such as an athletic shoe, according to the present invention includes an upper secured to a sole having a ground engaging portion with a wear resistant material composed of a thermoplastic polymer blended with from 0.1% to 2% of a fluorocarbon additive. In a preferred embodiment, the sole has ground engaging protrusions or cleats with each cleat composed of the wear resistant material, and the wear resistant material is a blend of TPU, such as Bayer Corporation's TEXIN 285™ or DESMONPAN 8785™, blended with 0.1% to 2% PFPE, such as DuPont KRYTOX™ general purpose oils and greases having GPL oil grades from 100-107, and more preferably from 101-105, inclusive.
Various advantages and features of novelty which characterize the invention are pointed out with particularity in the claims annexed hereto and forming a part hereof. However, for a better understanding of the invention, its advantages, and objects obtained by its use, reference should be made to the drawings which form a further part hereof, and to the accompanying descriptive matter, in which there are illustrated and described preferred embodiments of the invention.
REFERENCES:
patent: 4481333 (1984-11-01), Fleisher et al.
patent: 5143963 (1992-09-01), Sterling et al.
patent: 5286773 (1994-02-01), Sterling et al.
patent: 5632057 (1997-05-01), Lyden
patent: 5643516 (1997-07-01), Raza et al.
patent: 5663127 (1997-09-01), Flynn et al.
patent: 5700843 (1997-12-01), Valoppi
patent: 5704137 (1998-01-01), Dean et al.
patent: 5832636 (1998-11-01), Lyden et al.
patent: 5864968 (1999-02-01), Mann
patent: 60-104161 (1985-06-01), None
Abstract only of JP960271618.
Abstract only of EP113114.
Kosinski Leonard Edward Raymond
Krstic Ruzica
Banner & Witcoff , Ltd.
Cain Edward J.
Nike Inc.
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