Durable electrooptic devices comprising ionic liquids

Optical: systems and elements – Optical modulator – Light wave temporal modulation

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C359S270000, C359S321000, C252S583000, C252S586000

Reexamination Certificate

active

06961168

ABSTRACT:
Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF3SO3−), bis(trifluoromethylsulfonyl)imide ((CF3SO2)2N−), bis(perfluoroethylsulfonyl)imide ((CF3CF2SO2)2N−) and tris(trifluoromethylsulfonyl)methide ((CF3SO2)3C−). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes.

REFERENCES:
patent: 4671619 (1987-06-01), Kamimori et al.
patent: 4902108 (1990-02-01), Byker
patent: 5099356 (1992-03-01), Ohsawa et al.
patent: 5140455 (1992-08-01), Varaprasad et al.
patent: 5142407 (1992-08-01), Varaprasad et al.
patent: 5500760 (1996-03-01), Varaprasad et al.
patent: 5604626 (1997-02-01), Teowee et al.
patent: 5729379 (1998-03-01), Allemand et al.
patent: 5827602 (1998-10-01), Koch et al.
patent: 5838483 (1998-11-01), Teowee et al.
patent: 5864419 (1999-01-01), Lynam
patent: 5940201 (1999-08-01), Ash et al.
patent: 5998617 (1999-12-01), Srinivasa et al.
patent: 6045724 (2000-04-01), Varaprasad et al.
patent: 6067184 (2000-05-01), Bonhote et al.
patent: 6118572 (2000-09-01), Kostecki et al.
patent: 6122093 (2000-09-01), Lynam
patent: 6141137 (2000-10-01), Byker et al.
patent: 6172794 (2001-01-01), Burdis
patent: 6178034 (2001-01-01), Allemand et al.
patent: 6188505 (2001-02-01), Lomprey et al.
patent: 6241916 (2001-06-01), Claussen et al.
patent: 6245262 (2001-06-01), Varaprasad et al.
patent: 6246505 (2001-06-01), Teowee et al.
patent: 6266177 (2001-07-01), Allemand et al.
patent: 6297900 (2001-10-01), Tulloch et al.
patent: 6310714 (2001-10-01), Lomprey et al.
patent: 6317248 (2001-11-01), Agrawal et al.
patent: 6327070 (2001-12-01), Heuer et al.
patent: 6344918 (2002-02-01), Berneth et al.
patent: 6362914 (2002-03-01), Baumann et al.
patent: 6365301 (2002-04-01), Michot et al.
patent: 6369934 (2002-04-01), Bechinger et al.
patent: 6372159 (2002-04-01), Berneth et al.
patent: 6420036 (2002-07-01), Varaprasad et al.
patent: 6519072 (2003-02-01), Nishikitani et al.
patent: 6525861 (2003-02-01), Roberts et al.
patent: 6605239 (2003-08-01), Fitzmaurice et al.
patent: 6816298 (2004-11-01), Nishikitani et al.
patent: 2002/0012155 (2002-01-01), Baumann et al.
patent: 2003/0030883 (2003-02-01), Giri et al.
patent: 08329479 (1998-06-01), None
patent: 0193363 (2001-12-01), None
patent: 0127690 (2001-04-01), None
patent: 0163350 (2001-08-01), None
Charles M. Gordon, “New Developments in Catalysis Using Ionic Liquids,” Applied Catalysis A: General, vol. 222, pp. 101-117, 2001.
Martyn J. Earle, Paul B. McCormac, and Kenneth R. Seddon, “Diels-Alder Reactions in Ionic Liquids,” Green Chemistry, pp. 23-25, Feb. 1999.
J. Sun, M. Forsyth, and D. R. Macfarlane, “Room-Temperature Molten Salts Based on the Quaternary Ammonium Ion,” J. Phys. Chem. B. vol. 102, pp. 8858-8865, 1998.
Yu. F. Pugachev, I.V. Neverov, “An Electrochromic System Based on Methyl Viologen Influence of the Polymer, Base Electrolyte, and Solvent Type on its Chief Characteristics,” Ul'yanovsk Polytechnic Institute. Translated from Elektrokhimiya, vol. 22, No. 1, pp. 58-62, Jan. 1986.
“Ultraviolet Stabilizers,” Modern Plastics World Encyclopedia, pp. C-120-C-122, 2001.
Mark J. Muldoon, Andrew J. McLean, Charles M. Gordon, and Ian R. Dunkin, “Hydrogen Abstraction From Ionic Liquids by Benzophenone Triplet Excited States,” Chem. Commun., pp. 2364-2365, 2001.
D. Behar, P. Neta, and Carl Schultheisz, “Reaction Kinetics in Ionic Liquids as Studied by Pulse Radiolysis: Redox Reactions in the Solvents Methyltributylammonium Bis(trifluoromethylsulfonyl)imide and N-Butylpyridinium Tetrafluoroborate,” J. Phys. Chem. A, vol. 106, pp. 3139-3147, 2002.
Mark Niemeyer, “σ-Donor Versus η6-π-Arene Interactions in Monomeric Europium(II) and Ytterbium(II) Thiolates—An Experimental and Computational Study,” Eur. J. Inorg. Chem., pp. 1969-1981, 2001.
A. W. Czanderna, D. K. Benson, G. J. Jorgensen, J.-G. Zhang, C. E. Tracy, and S. K. DEB, “Durability Issues and Service Lifetime Prediction of Electrochromic Windows for Buildings Applications,” Solar Energy Materials & Solar Cells, vol. 56, pp. 419-436, 1999.
Dave Thieste, Harlan J. Byker, Kelvin Baumann, and Ramanujan Srinivasa, “Near Infrared-Absorbing Electrochromic Compounds and Devices Comprising the Same,” PCT Application WO 99/45081, published Sep. 10, 1999.
Clemens Bechinger, Suzanne Ferrere, Arie Zaban, Julian Sprague, and Brian A. Greeg, “Photoelectrochromic Windows and Displays,” Nature, vol. 383, pp. 608-610, Oct. 1996.
Gimtong Teowee, Todd Gudgel, Kevin McCarthy, Anoop Agrawal, Pierre Allemand, John Cronion, “User Controllable Photochromic (UCPC) Devices,” Electrochimica Acta, vol. 44, pp. 3017-3026, 1999.
Zhifeng Ding, Bernadette M. Quinn, Santosh K. Haram, Lindsay E. Pell, Brian A. Korgel, Allen J. Bard, “Electrochemistry and Electrogenerated Chemiluminescence from Silicon Nanocrystal Quantum Dots,” Science, vol. 296, pp. 1293-1297, May 2002.
Sand Kwon Lee, Mark M. Richter, Lucjan Strekowsky, and Allen J. Bard, “Electrogenerated Chemiluminescence. 61. Near-IR Electrogenerated Chemiluminescence, Electrochemistry, and Spectroscopic Properties of a Heptamethine Cyanine Dye in MeCN,” Analytical Chemistry, vol. 69, pp. 4126-4133, 1997.
Zhifeng Ding, “Electrochemistry and Electrogenerated Chemiluminescence from Silicon Nanocrystal Quantum Dots,” Science, vol. 296, pp. 1293-1297, May 2002.
Sang Kwon Lee, “Electrogenerated Chemiluminescence. 61. Near-IR Electrogenerated Chemiluminescence, Electrochemistry, and Spectroscopic Properties of a Heptamethine Cyanine Dye in MeCN,” Analytical Chemistry, vol. 69, pp. 4126-4133, 1997.
Alexander Michaelis, Horst Berneth, Dietrich Haarer, Serguei Kostromine, Ralph Neigl, and Ralph Schmidt, “Electrochromic Dye System for Smart Window Applications,” Adv. Mater., vol. 13, No. 23, Dec. 3, 2001.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Durable electrooptic devices comprising ionic liquids does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Durable electrooptic devices comprising ionic liquids, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Durable electrooptic devices comprising ionic liquids will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3482459

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.