Dry toners comprising amphipathic copolymeric binder having...

Radiation imagery chemistry: process – composition – or product th – Electric or magnetic imagery – e.g. – xerography,... – Post imaging process – finishing – or perfecting composition...

Reexamination Certificate

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C430S109300, C430S110200, C430S137120

Reexamination Certificate

active

07318988

ABSTRACT:
The invention provides dry electrographic toner compositions comprising toner particles. The toner particles comprise polymeric binder comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions prepared from an organosol reaction process utilizing a liquid carrier reaction medium having a Kauri-Butanol number less than about 30 mL. The S material portion comprises at least one soluble component and at least one non-sorptive component, wherein the non-sorptive component is the reaction product of monomers having an absolute difference in Hildebrand solubility parameter from the liquid carrier of about 3.0 MPa1/2or greater. Additionally, dry electrographic toner compositions are provided wherein the toner particles comprise polymeric binder comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions. The S material portion of the amphipathic copolymer has an average Hildebrand solubility parameter of from about from about 16 MPa1/2to about 17.3 MPa1/2, and comprises at least one non-sorptive component having an average Hildebrand solubility parameter that is at least about 0.4 MPa1/2greater than the average Hildebrand solubility parameter of the S material portion.The resulting dry toner composition can exhibit excellent final image durability characteristics, and can also provide excellent images at low fusion temperatures on a final image receptor.

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Commonly assigned U.S. Appl. No. 10/975,557, filed Oct. 28, 2004 entitled “Liquid Toners Comprising Amphipathic Copolymeric Binder Having Insoluble Components in the Shell Portion Thereof”, in the Name of Jiayi Zhu et al.

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