Dry mix for water based drilling fluid

Earth boring – well treating – and oil field chemistry – Earth boring – Contains organic component

Reexamination Certificate

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C507S103000, C507S106000, C507S107000, C507S138000, C507S140000, C507S141000

Reexamination Certificate

active

06818596

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The prior art relates to petroleum wells in general and to drilling fluids in particular.
2. Prior Art
Drilling muds or drilling fluids are used in drilling operations such as in the drilling of petroleum wells. The drilling apparatus comprises in the most general terms, a length of drill stem (the drill string) often having a rotary drill at its downhole end. Drilling fluid or “mud” is pumped through the well bore.
Every drilling mud is comprised of a base fluid and some combination of dry and or liquid components that are mixed into the base fluid to create a mud that has the desired components in the desired ratios. Typically, such mixing is done in the field, and involves the labor of many people and numerous bags, tanks, pails, mixing hoppers, mixing pumps, and hoses.
There are two main types of drilling mud: oil based muds (OBM) and water based muds (WBM). As their names imply, the two types of muds can be differentiated by the nature of their base fluids. Fresh or salt water makes up the base fluid in WBM's while diesel oil, mineral oils, or synthetic oils often serve as the base fluid for OBM's, although salt water is often emulsified into the base fluid with primary and secondary emulsifiers in OBM's.
The drilling mud must accomplish several tasks. One of the primary purposes of the drilling mud is lubrication. The drilling mud lubricates the drill bit, helping to prevent damage to the bit as it grinds through the earth. The drilling mud also lubricates the drill stem, preventing it from sticking to the walls of the well bore as it is rotated. Additionally, the drilling mud cools the bit and string, dissipating the heat generated by the drilling itself and the geothermal heat, where present.
As the drill bit rotates, it dislodges pieces of rock, clay, dirt, and etc, known as cuttings. Additionally, portions of the well bore may cave off from time to time. While such cavings are to be avoided, if possible, both the cavings and the cuttings must be removed. This is another function of the drilling fluid. As drilling mud is pumped through the well bore it picks up and carries these drill cuttings and cavings out of the well bore. Additionally, the drilling mud should be capable of suspending the cuttings in the drilling mud when circulation is stopped. If the drilling mud does not have enough gel strength to keep the cuttings in suspension, they will settle out of the drilling mud.
If the cuttings settle out of the drilling mud, they can collect in cutting beds—piles of cuttings and cavings that have collected at one point in the well bore. However, in directional drilling, the well bore can have one or more sections that are between horizontal and vertical. The low sides of these sections of the well bore are particularly susceptible to the formation of cutting beds, particularly in bends where the bore moves from a more vertical section to a more horizontal section. Cutting beds in these positions can bind the drill stem. This can impede rotation of the stem and impede steerage of the bit in directional drilling. Cutting beds can also impede the insertion of additional drill stem or the removal of drill stem that is already in place. Similarly, cutting beds can cause the bit or other downhole tools to become stuck as well. Thus, it is important for a drilling mud to minimize the rate at which cuttings fall out of suspension when the circulation of the drilling mud stops.
Another requirement of the drilling mud is to help hold up the well bore walls. The drill bit necessarily cuts a hole in the earth that is slightly larger than the diameter of the drill stem. The drilling mud circulating in the well bore provides support to the well bore walls and prevents them from collapsing.
Instability in the well bore is an especially frequent problem in shale formations. Shales are complex clay rich geological sediments. Their notorious instability is believed to arise from the fact that some of the minerals responsible for cementing the shale components together are at least partially soluble in water. Adding water to these components will cause them to swell and dissolve, thereby reducing the forces holding the shale together and resulting in its deterioration. Conversely, drying the shale will increase the cementing effect the minerals have on the shale, causing the shale to harden and strengthen. The instability of a shale will vary directly in proportion to the amount of time spent in open hole operation—that is, the amount of time with no casing separating the drilling mud in the well bore from the formation.
One clay mineral that is especially problematic is sodium montmorillonite, also known as swelling bentonite. Sodium montmorillonite is especially problematic because it expands to several times its original volume when it encounters water. Thus, the water in a WBM pumped through shale formation can cause the sodium montmorillonite in the well bore wall to swell substantially. Such swelling can weaken the bond between the clay particles and the other components of the shale. This can cause the well bore wall to slough off or to collapse altogether. Additionally, the swelling of the clay particles can cause the well bore diameter to shrink, such that it may restrict the drill string or actually cause the drill string or any number of downhole tools to become stuck. Also, when the clay particles enter the drilling mud and swell, they can increase the drilling mud viscosity beyond desirable levels, which can increase the well bore pressure, making the mud more difficult to pump and simultaneously increasing stress on the well bore, leading to increased risk of well bore erosion or collapse and/or loss of drilling fluid to the surrounding formation through the well bore walls. Shales high in sodium montmorillonite, and thus especially susceptible to the foregoing problems, are commonly encountered in the Gulf of Mexico and the North Sea.
When well bores are expected to encounter shale formations, drillers will often use an OBM to reduce the exposure of the shale to water. However, the cost of using an OBM is significantly greater than WBM's because of the cost of the base fluid. Additionally, OBM's and their cuttings are subject to more rigorous environmental treatment than their WBM counterparts.
Another function of the drilling mud is counteracting the pressure of the formation. When petroleum reservoirs are encountered during drilling, they may be under significant pressure. These pressures will tend to assault the bore wall, potentially causing it to implode and also potentially forcing the petroleum product into the well bore. One way of addressing the problem is by increasing the density of the drilling mud. This will counter the pressurized formations encountered downhole, neutralize the pressure on the well bore wall, and prevent the petroleum products from escaping into the well bore.
The well bore may pass through many different types of soil, rock, shale and sand. Although some of these formations will be pressurized as discussed above, others will not be pressurized or will be under less pressure than the drilling mud. In such cases, a common and expensive problem is the loss of drilling mud to the formation. Although problematic in WBM's and OBM's these types of losses are particularly troublesome in OBM's. However, with either mud type, the mud is lost in the same manner. Fractures or porous soil materials essentially act like leaks in the well bore, allowing the drilling mud to simply flow out of the bore. It is important to minimize such losses. To this end, the drilling mud is configured to deposit a thin filter cake on the walls of the well bore.
The filter cake is a thin layer of non-water permeable or semi-permeable material at the wall of the well bore. It seals fractures in the formation that open into the well bore and otherwise acts as a barrier between the well bore and the formation through which the well bore passes. To the extent that the formation is p

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