Dry chemical reprocessing method and dry chemical reprocessing a

Electrolysis: processes – compositions used therein – and methods – Electrolytic synthesis – Utilizing electrolyte system having two or more separate...

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205349, C25B 100

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active

060568658

ABSTRACT:
In a dry chemical reprocessing method, uranium type elements are electrolytically refined continuously. Molten cadmium in which these uranium type elements are dissolved is transferred to a rotating cathode electrolysis tank 30 for performing electrolytic refining. The rotating cathode electrolysis tank 30 is filled with molten cadmium, and a mixture of potassium chloride and lithium chloride. In the salt phase are placed a rotating cathode 32 and a receiving dish 36 for uranium type elements which deposit at the cathode, while in the molten cadmium phase a fixed anode 42 is installed. When uranium type elements deposited at the rotating cathode 32 have grown to at least a predetermined size, they are scraped off by a scraper 34 and collect in a receiving dish 36. These uranium type elements are sent to a U/salt separating tank 50 where uranium is separated from salts. The separated uranium and molten cadmium are aspirated by a pump 59, and sent to a Cd distiller 60 via a pipe 58a where the uranium type elements are recovered as their oxides and the cadmium is distilled off and recovered.

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Nawada et al. "Numerical simulation of minor actinide recovery behavior in batch procesing of spent metallic fuel by electrofining," Adv. Chem Eng. Nucl. Process Ind. (1994). No month available.

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