Dried catalytic systems for decomposition of organic hydroperoxi

Details Dried catalytic systems for decomposition of organic hydroperoxi Dried catalytic systems for decomposition of organic hydroperoxi

1995-03-03

1996-08-27

Evans, Joseph E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568798, 568815, 5689098, C07C 2900, C07C 3112, C07C 3322, C07C 3514

Patent

active

055503012

ABSTRACT:
Organic hydroperoxides are decomposed by drying a reaction mixture containing the organic hydroperoxide and an organic solvent such that said dried reaction mixture comprises approximately 1 weight percent or less of water and contacting the dried reaction mixture with a metal organic ligand catalyst under hydroperoxide decomposition conditions. An organic co-solvent for the hydroperoxide may also be used. Particularly effective catalysts are cobalt acetylacetonates and ruthenium acetylacetonates and combinations thereof.

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