Double ylide complexes of metals and process for making them

Details Double ylide complexes of metals and process for making them Double ylide complexes of metals and process for making them

1978-01-12

1980-01-22

Sneed, Helen M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260429R, 2604299, 260439R, 260448A, 2606065P, C07F 112

Patent

active

041850289

ABSTRACT:
Double ylide complexes of metals are made by reacting trimethylphosphin-imino-dimethyl-methylene phosphorane of the formula ##STR1## with one or more compounds of the metals nickel, palladium, platinum, gold, zinc, cadmium, aluminum, gallium, indium, thallium, magnesium or lithium.
The novel double ylide complexes comprise various metal-bis[nitrido-bis(dimethylphosphonium methylides)], dimethyl-metal[nitrido-bis(dimethylphosphonium methylides)], and lithium-[nitrido-bis(dimethylphosphonium methylide)].

REFERENCES:
patent: 2998416 (1961-08-01), Mendel
patent: 3414624 (1968-12-01), Peterson et al.
patent: 4083875 (1978-04-01), Schmidbaur et al.
patent: 4097509 (1978-06-01), Schmidbaur et al.
Chemical Abstracts, 85 160249w (1976).

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