Double perovskite catalysts for oxidative coupling

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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502302, 502304, 502525, B01J 2310, B01J 2378, B01J 2384

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active

049886606

ABSTRACT:
Alkali metal doped double perovskites containing manganese and at least one of cobalt, iron and nickel are useful in the oxidative coupling of alkane to higher hydrocarbons.

REFERENCES:
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patent: 4239658 (1980-11-01), Mitchell, III et al.
Keller, G. E., et al., "Synthesis of Ethylene Via Oxidative Coupling of Methane", J. Cataly., vol. 73, pp. 9-19 (1982).
Garcia, et al., "Direct Catalytic Synthesis of Ethylene from Methane", React. Kinet. Catal. Lett., vol. 28, 481 (1985).
Sofranko, J., et al., "The Oxidative Conversion of Methane to Higher Hydrocarbons", J. Cataly., vol. 103, pp. 302-310 (1987).
Jones, C. A., et al., "The Oxidative Conversion of Methane to Higher Hydrocarbons Over Alkali-Promoted Mn/SiO.sub.2 ", J. Cataly., vol. 103, 311 (1987).
Gaffney A., et al., "Oxidative Coupling of Methane over Sodium Promoted Praseodymium Oxide", J. Cataly., vol. 114, pp. 422-432 (1988).
Vallet-Regi, M., et al., "Synthesis and Characterization of a New Double Perovskite: LaCaMnCoO.sub.6 ", J. Chem. Soc., Dalton Trans., 775 (1988).

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