Double metal cyanide complex catalysts modified with Group IIA c

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Inorganic carbon containing

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502172, 502175, 502183, 502307, 502326, 502340, 502200, B01J 2726

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active

059522615

ABSTRACT:
Highly active double metal cyanide complex catalysts useful for epoxide polymerization are prepared by reacting zinc chloride or other metal salt with potassium hexacyanocobaltate or other metal cyanide salt in the presence of a Group IIA compound such as calcium chloride.

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Schuchardt et al., "Preparation of High Molecular Weight Polyols Using Double Metal Cyanide Catalysts," 32nd Annual Polyurethane Technical Marketing Conference, Oct. 1-4, 1989, pp. 360-364.
Herold et al., "Hexacyanomeltalate Salt Complexes as Catalysts for Epoxide Polymerizations," Advances in Chemistry Series, No. 128, Polymerization Kinetics and Technology, 1973, pp. 208-229.
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