Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode or plural tablets – pellets or discs
Reexamination Certificate
2001-10-24
2004-02-17
Weiner, Laura (Department: 1745)
Chemistry: electrical current producing apparatus, product, and
Current producing cell, elements, subcombinations and...
Electrode or plural tablets, pellets or discs
C429S219000, C429S220000, C429S221000, C429S223000, C429S224000, C429S231100, C429S231300, C429S231500, C429S231700, C429S245000, C429S330000, C429S328000, C429S332000, C429S336000, C429S231950
Reexamination Certificate
active
06692865
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of Invention
This invention relates to the conversion of chemical energy to electrical energy. In particular, the present invention relates to a new sandwich cathode design having two cathode active materials provided in two different mixtures. The first cathode active material is of a relatively low energy density but of a relatively high rate capability while the second cathode active material has a relatively high energy density but a relatively low rate capability. The cathode is built in a sandwich configuration having a first cathode structure sandwiched between two current collectors. Then, a second cathode structure is provided in contact with at least the other side of one of the current collectors, and preferably facing the anode. In each of the first and second cathode structures, the weight percent of the first and second active materials equals 100. For example, the first cathode structure has, by weight: (100−y)% first cathode active material+y% second cathode active material, where 0≦y≦100, and the second cathode structure has: (100−x)% first cathode active material+x% second cathode active material, where 0≦x≦100, and wherein x<y, y<x or x=y.
The present cathode design is useful in applications where a premium is places on increased energy density, such as in power sources associated with implantable medical devices, while providing relative safety under short circuit conditions.
2. Prior Art
The capacity of an electrochemical cell is not only dependent on the electrode assembly design and packing efficiency, it is also dependent on the type of active materials used. For example, it is generally recognized that for lithium cells, silver vanadium oxide (SVO) and, in particular, &egr;-phase silver vanadium oxide (AgV
2
O
5.5
), is preferred as the cathode active material. This active material has a theoretical volumetric capacity of 1.37 Ah/ml. By comparison, the theoretical volumetric capacity of CF
x
material (x=1.1) is 2.42 Ah/ml, which is 1.77 times that of &egr;-phase silver vanadium oxide.
An attempt to use high capacity materials, such as CF
x
, by mixing it with a high rate cathode material, such as SVO, is reported in U.S. Pat. No. 5,180,642 to Weiss et. al. However, electrochemical cells made from such cathode composites have lower rate capability. Increasing the cell's theoretical capacity by using CF
x
as part of the cathode mix is in part canceled by lowering of its power capability in a high rate discharge application.
U.S. Pat. No. 5,614,331 to Takeuchi et al., which is assigned to the assignee of the present invention and incorporated hereby by reference, describes a method of using a medium rate CF
x
cell to power the circuitry of an implantable defibrillator while simultaneously using a SVO cell to provide the power supply under high rate applications for the device. The advantage of this method is that all of the high power SVO energy is reserved for the high power application such as charging a capacitor while the device monitoring function, for example for monitoring the heart beat, which requires generally low power requirements, is provided by the high capacity CF
x
system. However, this battery construction requires a very careful design to balance the capacities of the high power cell (SVO) and the low power cell (CF
x
) with both cells reaching end of service life at or near the same time. Such a balance, nevertheless, is very difficult to achieve due to the variable device usage requirements of a particular patient.
SUMMARY OF THE INVENTION
Accordingly, the object of the present invention is to improve the performance of lithium electrochemical cells by providing a new concept in electrode design. The new electrode configuration is especially useful in applications where increased energy density is desired while providing relative safety under short circuit conditions. Also, the cell has a predictable end of life, which is useful for scheduling cell replacement procedures, such as in implantable medical device applications.
To fulfill these needs, a new sandwich cathode design is provided having a first cathode structure of a first cathode active material of a relatively low energy density but of a relatively high rate capability, for example SVO, mixed with a second cathode active material having a relatively high energy density but a relatively low rate capability, for example CF
x
, with the percentage of SVO being less than that of CF
x
and sandwiched between two current collectors. Then, a second cathode mixture of SVO and CF
x
active materials is contacted to the outside of the current collectors. However, the percentage of SVO to CF
x
is greater in the second structure than in the first. Such an exemplary cathode design might look like, by weight:
(100−y)% SVO+y% CF
x
, wherein 0≦y≦100/current collector/(100−x)% SVO+x% CF
x
, wherein 0≦x≦100/current collector/(100−y)% SVO+y% CF
x
, wherein 0≦y≦100, and wherein y<x, x<y or x=y.
These and other objects of the present invention will become increasingly more apparent to those skilled in the art by reference to the following description.
REFERENCES:
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patent: 4161063 (1979-07-01), Goebel et al.
patent: 4292357 (1981-09-01), Erisman et al.
patent: 4324828 (1982-04-01), Ebato et al.
patent: 4409730 (1983-10-01), Goebel
patent: 4439916 (1984-04-01), Faber
patent: 5180642 (1993-01-01), Weiss et al.
patent: 5571636 (1996-11-01), Ohta et al.
patent: 5582935 (1996-12-01), Dasgupta et al.
patent: 5639568 (1997-06-01), Pedicini et al.
patent: 5658694 (1997-08-01), Charkey
patent: 5667916 (1997-09-01), Ebel et al.
patent: 5670276 (1997-09-01), Takeuchi et al.
patent: 5716422 (1998-02-01), Muffoletto et al.
patent: 5744258 (1998-04-01), Bai et al.
patent: 5863676 (1999-01-01), Charkey et al.
patent: 5993999 (1999-11-01), Rivers et al.
patent: 6551747 (2003-04-01), Gan
Gan Hong
Takeuchi Esther S.
Scalise Michael F.
Weiner Laura
Wilson Greatbatch Ltd.
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