Divot free shallow trench isolation process

Semiconductor device manufacturing: process – Formation of electrically isolated lateral semiconductive... – Grooved and refilled with deposited dielectric material

Reexamination Certificate

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C438S221000, C438S296000

Reexamination Certificate

active

06197659

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates generally to processes for forming isolation regions in semiconductor devices, and more specifically to a process of fabricating a shallow trench isolation (STI) structure in a semiconductor device.
2. Description of the Prior Art
As semiconductor device dimensions are decreased, and device density increases, it becomes more difficult to efficiently and reliably fabricate isolation structures for separating active areas of the device. One common method of forming isolation structures for semiconductor devices is referred to as localized oxidation of silicon (LOCOS). However, the limits of the standard LOCOS process have motivated the development of new isolation processes. A trench isolation process is now widely used as it uses a fully recessed oxide, has no bird's beaks, is fully planar, and does not suffer from the field oxide thinning effect. However, the trench isolation process still suffers from problems such as “corners” effects at the trench edge that can increase device leakage current, especially when the trench is recessed.
U.S. Pat. No. 5,733,383, issued to Fazan, et al. on Mar. 31, 1998 discloses a method of using pacers used to form isolation trenches with improved corners. The trench for isolating active devices on a semiconductor substrate, is formed by creating a trench which has a peripheral edge, and disposing an isolating material in the trench. The isolating material extends over the peripheral edge of the trench, thereby covering at least a portion of the substrate surrounding the trench, and substantially limiting leakage of the active devices disposed on the substrate.
FIG. 1
shows a cross-sectional view at
10
of a typical prior art shallow trench isolation (STI) structure including isolation material
12
deposited within a trench
14
formed in a semiconductor substrate
16
, the STI structure
10
having a recess, or divot,
18
formed between the isolation material
12
and the edge of the trench
14
. When the isolation material
12
is etched, the recess, or divot,
18
frequently results wherein little or no isolating material
12
remains at the “corners” of the trench
14
. The exposed “corners” are potential points of current leakage between regions of the active areas (not shown) of. The current leakage and other effects of the exposed corners are referred to as “corners effects”. As is well understood in the art, the recess has a negative impact on I
D
V
G
characteristics of STI junctions.
Many prior art processes have been developed for manufacturing STI structures wherein the corners effect is minimized.
FIGS. 2A through 2H
are cross-sectional views illustrating a progression of manufacturing steps in accordance with an exemplary prior art process of manufacturing an STI structure having a smooth trench profile achieved by forming spacers around the periphery of the trench to form a dome like structure over the trench.
Referring to
FIG. 2A
, an insulating layer
30
is formed over a semiconductor substrate
32
in accordance with initial steps in accordance with the prior art process of manufacturing the STI structure. The insulating layer
30
is typically formed using an oxide, commonly referred to as a pad oxide. However, other suitable insulating materials are also known to be used. A nitride masking layer
34
is disposed over the insulating layer
30
. Although the masking layer
34
is usually formed using a material having insulative properties (e.g., silicon nitride), conductive materials such as polysilicon and polysilicon
itride may also be used to form the masking layer
34
.
Initial steps in defining active areas
36
and trench areas
38
of the semiconductor substrate
32
include: applying a photo-resistive mask
40
over the nitride masking layer
34
; etching to remove portions of the nitride masking layer
34
and insulating layer
30
in the trench area
38
; etching to remove portions of the nitride masking layer
34
and insulating layer
30
in the trench area
38
; etching further to remove a portion of the substrate
32
; and subsequently removing the photo-resistive mask
40
. Reactive ion etching (RIE) is typically used in this phase of the STI process to etch portions of layers
30
and
34
, and portions of the substrate
32
.
FIG. 2B
shows a cross-sectional view of a trench
44
formed in the substrate
32
as a result of the step of etching an exposed portion of the substrate
32
in the trench area after the exposed portions of layers
30
and
34
. The trench
44
has sidewalls which may be substantially vertical to the substrate
32
, or which may be slightly sloped as shown. A first oxide layer
48
may be grown or deposited in the trench
44
via a rapid thermal oxidation (RTO) process, thereby lining the sidewalls and bottom of the trench
44
and providing greater resistance to cracking, and for passivating the trench sidewalls.
Referring to
FIG. 2C
, a second oxide layer
50
is deposited in the trench
44
, and over the remaining portions of the insulating layer
30
, and nitride masking layer
34
. The second oxide layer
50
functions as an insulator, thereby providing isolation of the various electrical devices which may be fabricated on the substrate
32
. The second oxide layer
50
is typically formed by a thick layer of oxide such as tetraethyl orthosilicate (TEOS), CVD-oxide, borophosphosilicate glass (BPSG), nitride, a combination thereof, or a similar insulating material. Other materials have also been found to be effective for use in isolation trenches, such as, for example, a combination of nitride and oxide, or polysilicon which has been oxidized.
FIG. 2D
shows a cross-sectional view of the STI structure of
FIG. 2C
after planarization steps have been performed. Planarization may be accomplished by any of a variety of suitable methods, such as chemical-mechanical polishing (CMP), dry etching, or a combination thereof. As a result of the planarization steps, the top surface of the nitride masking layer
34
is exposed. The structure of
FIG. 2E
results after the nitride masking layer
34
is removed via a wet etching process. A portion of the second oxide layer
50
protrudes above the substrate
32
after the nitride masking layer
34
has been etched away. The protruding portion of the second oxide layer
50
has substantially vertical sides. If the insulating layer
30
were to be removed at this point using a wet etching method, a recess would be formed as shown in FIG.
1
.
In order to avoid the recess and accompanying corners effects, a third oxide layer
52
may be deposited over the insulating layer
30
and second oxide layer
50
as shown in FIG.
2
F. Typically, the material used to form the third oxide layer
52
has chemical properties which are substantially similar to those of the material used to form the second oxide layer
50
. The third oxide layer
52
is usually deposited in accordance with a conventional chemical vapor deposition (CVP) method. The third oxide layer
52
may be formed by depositing TEOS, nitride with TEOS, or borophosphosilicate glass (BPSG). CVD-oxide may be employed. Other suitable deposited dielectrics can be used, as well as polysilicon which is subsequently oxidized. The third oxide layer
52
usually conforms to the profile of the structure, as shown in FIG.
2
F. The conformal properties of the third oxide layer
52
enable the self-alignment of spacers as further described below.
A partial spacer etching step is performed, typically using dry etching, to remove all but a portion of the third oxide layer
52
thereby forming a spacer
54
surrounding the trench. Dry etching is used because it tends not to damage the active area regions which may also be disposed on the substrate. The chemical properties of the spacers
54
are substantially similar to those of the material used to form the second oxide layer
50
. The spacers
54
are located on the surface of the substrate
32
at the corners of the trench, and are self-aligned to the trench

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