Dithioacid rhenium sulfide dimer compositions

Details Dithioacid rhenium sulfide dimer compositions Dithioacid rhenium sulfide dimer compositions

1989-07-26

1990-09-04

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

556 49, C07F 1300

Patent

active

049546457

ABSTRACT:
Briefly stated, the present invention encompasses a new class of rhenium 1,1-dithioacid complexes and their method of preparation. The complexes have the general formula [L.sub.2 Re(.mu.-S)].sub.2 wherein L is a dithioacid or similar ligand, and .mu. denotes the fact that the sulfur atoms in the core of the complex bridge the two rhenium atoms in the complex. Thus, the core structure for such typical compounds is generally of the form: ##STR1## where the dangling valences are associated with the sulfur atoms of a 1,1-dithioacid, L.

REFERENCES:
Rowbottom et al., "J. Chem. Soc. Dalton", 1974, pp. 684-689.
Rowbottom et al., "J. Chem. Soc. Dalton", 1972, pp. 826-830.
Belousov et al., "Reset. Kinet. Catal. Lett.", 21(3), pp. 371-375 (1982).
Fletcher et al., "J. Chem. Soc. Dalton", 1974, pp. 486-489.
Griffith, "J. Chem. Soc. A," 2, pp. 211-218 (1969).
Nitra et al., "Z. Anoy. Ally. Chem.", 548 (1982), pp. 217-224.

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