Ditertiary butyl peroxide recovery

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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549541, C00F30119, C00F30132

Patent

active

048108090

ABSTRACT:
It has been discovered in accordance in accordance with the present invention that a tertiary butyl alcohol/ditertiary butyl peroxide azeotrope may be recovered from a product containing tertiary butyl alcohol and ditertiary butyl peroxide by distilling the tertiary butyl alcohol product to obtain an overhead fraction containing substantially all of the ditertiary butyl peroxide/tertiary butyl alcohol azeotrope and other contaminants.
It has been further discovered in accordance with the present invention that the ditertiary butyl peroxide can be recovered from the distillate fraction by extraction with ethylene glycol (e.g., in a countercurrent ethylene glycol extraction tower) to provide a ditertiary butyl peroxide product of any desired degree of purity.

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