Disproportionation of rosin in the presence of dithiin derivativ

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 97, 260106, 260108, 260453RY, 549 20, 549 21, 549 22, C09F 104, C07C 3908

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active

042658071

ABSTRACT:
Disclosed is a method of disproportionating rosin comprising heating said rosin in the presence of a dithiin derivative such, for example, as 2,5-diphenyl dithiin. The method can be carried out at about 150.degree. C. to about 300.degree. C. for about 1 hour to about 10 hours with the longer reaction time corresponding to the lower temperatures. Preferably, the process is run at about 260.degree. C. to about 300.degree. C. for about 3 to 8 hours.

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patent: 3417071 (1968-12-01), Wheelers
patent: 3423389 (1969-01-01), Wheelers
patent: 3649612 (1972-03-01), Scharrer
patent: 3872073 (1975-03-01), Thorpe et al.
patent: 3929703 (1975-12-01), Weymann et al.
patent: 4126604 (1978-11-01), Alford et al.

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