Disproportionating method of trimethylamine

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564470, C07C20964

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active

056081146

ABSTRACT:
Upon subjecting trimethylamine with ammonia and optionally, a methylamine to a disproportioning reaction to reduce the proportion of the trimethylamine, use of a zeolite as a catalyst, said zeolite being mordenite, clinoptilolite or the like at least 80% of whose ion-exchangeable cations being in the form of hydrogen ions, makes it possible to efficiently conduct the reaction at a low reaction temperatures and also to suppress by-production of impurities such as acetonitrile.

REFERENCES:
patent: 4398041 (1983-08-01), Cochran et al.
patent: 4485261 (1984-11-01), Ashina et al.
patent: 4806689 (1989-02-01), Gier et al.
patent: 5243078 (1993-09-01), Agrawal
patent: 5344989 (1994-09-01), Corbin et al.
Applied Catalysis, vol. 32, 1987, pp. 361-366, M. Keane et al, "Selective Synthesis of Dimethylamine Over Small Pore Zeolites".
Patent Abstracts of Japan, vol. 7, No. 135 (C-170), Jun. 11, 1983 (JP-A-58049340 (Toyo Soda Kogyo KK) Mar. 23, 1983.) *Abstract*.

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