Dispersion enhanced PT group metal catalysts

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Mixture is exhaust from internal-combustion engine

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B01D 4500, B01D 4600

Patent

active

051961750

ABSTRACT:
A method of making a three-way catalyst based on platinum group metals, comprising: (a) impregnating an alumina substrate with a platinum group metal ion by contacting such substrate with an aqueous solution containing the platinum group metal in an amount of 0.1-5% by weight of alumina substrate and a water soluble acid that forms RCOOH with R being an alkyl or equivalent, said acid being present in an amount of 10-120% by weight of the alumina substrate, the pH of said solution being less than 4.0; and (b) drying and calcining the wetted substrate without sintering said substrate.
The three-way catalyst construction based on platinum group metals has enhanced catalytic activity. It comprises an alumina substrate and a platinum group metal impregnation layer thereover, said impregnation layer being comprised of raft-like particle structures, each having increased metal density resulting from the nesting of both small and large metal particles within a given volume.

REFERENCES:
patent: 4171287 (1979-10-01), Keith
patent: 4678770 (1987-07-01), Wan et al.

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