Dispersing agent comprising vinyl alcohol polymer having...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

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Details

C525S059000, C525S060000, C526S082000, C526S084000, C524S394000, C524S563000, C524S570000, C524S579000

Reexamination Certificate

active

10769039

ABSTRACT:
A dispersing agent suitable for suspension polymerization of vinyl compounds, comprising a polyvinyl alcohol resin containing carbonyl groups in its molecule and having a block character of remaining fatty acid ester groups of at least 0.5 and an absorbance of at least 0.1 measured at each of wavelengths of 215 nm, 280 nm and 320 nm with respect to a 0.1% by weight aqueous solution of the polyvinyl alcohol resin, wherein the ratio of absorbance at 320 nm to absorbance at 280 nm is at least 0.3. The dispersing agent has an excellent surface activity and can suppress foaming which may occur in the suspension polymerization of vinyl compounds.

REFERENCES:
patent: 6448321 (2002-09-01), Tokita
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Translation in part of JP-A-8-283313, published Oct. 29, 1996 Filing No. 7-89904/Filing Date Apr. 17, 1995.
Translation in part of JP-A-8-269112, published Oct. 15, 1996 Filing No. 7-103049/Filing Date Apr. 3, 1995.
“Thermally Modified Poly (Vinyl Alcohol) as a Protective Colloid in Suspension Polymerization of Vinyl Chloride” by M. Fabini Chem. Papers 47 (1) pp. 60-63 (1993).
“The Influence of Poly(vinyl alcohol) Suspending Agents on Suspension Poly(vinyl chloride) Morphology” by S. Ormondroyd British Polymer Journal, vol. 20, No. 4, 1988, pp. 353-359.
“Vinyl Chloride Suspension Polymerisation and the Control of Polymer Properties” by P.V. Smallwood, Makromol. Chem., Macromol. Symp. 29, 1-19 (1989), pp. 1-19.

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