Disazo dye composition

Bleaching and dyeing; fluid treatment and chemical modification – Reactive dye composition – process – or product – Alkylene sulfato – halotriazine – halodiazine,...

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8641, 8681, 8918, 260185, C09B 6200, C09B 2700

Patent

active

042577705

ABSTRACT:
A dye composition comprising at least one disazo dye of the formula (I) expressed in the form of a free acid, ##STR1## wherein each X.sub.1 and X.sub.2 is --SO.sub.2 CH.sub.2 CH.sub.2 OCOCH.sub.3, --SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H or --SO.sub.2 CH.dbd.CH.sub.2, provided that at least one of X.sub.1 and X.sub.2 is --SO.sub.2 CH.sub.2 CH.sub.2 OCOCH.sub.3, and at least one disazo dye of the formula (II) expressed in the form of a free acid, ##STR2## Wherein each Y.sub.1 and Y.sub.2 is --SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H, --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 OH, provided that one of Y.sub.1 and Y.sub.2 is --SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H or --SO.sub.2 CH.dbd. CH.sub.2, is produced by diazotizing a mixture of 4-aminophenyl-.beta.-sulfatoethylsulfone and 4-aminophenyl-.beta.acetoxyethylsulfone in a weight ratio of 30 to 70: 70 to 30 with a nitrite, and coupling the resulting mixture of the diazonium salts with 1-amino-8-naphthol-3,6-disulfonic acid. The dye composition is suitable for dyeing natural or regenerated cellulosic fiber materials in black.

REFERENCES:
patent: 3114754 (1963-12-01), Lodge et al.
Vewkataraman, K, "The Chemistry of Synthetic Dyes", vol. VI, Academic Press, 1972, pp. 36-37; 46; 49; 50-51;259.
Colour Index, vol. 3, (Third Edition), C. I. Reactive Black 5, pp. 3, 5, 48.

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