Chemistry of inorganic compounds – Carbon or compound thereof – Elemental carbon
Reexamination Certificate
2003-02-24
2009-11-10
Hendrickson, Stuart (Department: 1793)
Chemistry of inorganic compounds
Carbon or compound thereof
Elemental carbon
C428S367000, C977S742000, C977S750000
Reexamination Certificate
active
07615204
ABSTRACT:
Long, macroscopic nanotube strands or cables, up to several tens of centimeters in length, of aligned single-walled nanotubes are synthesized by the catalytic pyrolysis of n-hexane using an enhanced vertical floating catalyst CVD technique. The long strands of nanotubes assemble continuously from ropes or arrays of nanotubes, which are intrinsically long. These directly synthesized long nanotube strands or cables can be easily manipulated using macroscopic tools.
REFERENCES:
patent: 5458784 (1995-10-01), Baker et al.
patent: 6333016 (2001-12-01), Resasco et al.
patent: 6749827 (2004-06-01), Smalley et al.
Jiang et al. “Spinning continuous carbon nanotube yarns” Oct. 24, 2002, Nature, vol. 419, p. 801.
H. W. Zhu, et al., “Direct Synthesis of Long Single-Walled Carbon Nanotube Strands,”Science, vol. 296, pp. 884-886 (May 3, 2002).
Bingqing Wei, et al., “Structural Characterizations of Long Single-Walled Carbon Nanotube Strands,”Nano Letters, vol. 2, No. 10, pp. 1105-1107 (2002).
Yan-Hui Li, et al., “Self-organized Ribbons of Aligned Carbon Nanotubes,”Chem. Mater., 14, pp. 483-485 (2002).
Lijie Ci, et al., “Preparation of carbon nanofibers by the floating catalyst method,”Carbon38, pp. 1933-1937 (2000).
Cheng et al, Chemical Physics Letters, Jun. 19, 1998, vol. 289, pp. 602-610.
Cheng et al, Applied Physics Letters, Jun. 22, 1998, vol. 72, No. 25, pp. 3282-3284.
B. Vigolo, et al.,Science290, 1331 (2000).
M. Endo et al.,J. Phys. Chem. Solid54, 1841 (1993).
R. Andrews et al,Chem Phys. Lett. 303, 467 (1999).
J.E. Fischer et al,Phys. Rev. B55, R4921 (1997).
P.H. Zhang, P.E. Lammert, V.H. Crespi,Phys. Rev. Lett. 81, 5346 (1998).
M. M. J. Treacy, T.W. Ebbesen, J.M. Gibson,Nature381, 678 (1996).
E.W. Wong, P.E. Sheehan, C.M. Lieber,Science277, 1971 (1997).
M.F. Yu, B.S. Files, S. Areepalli, R.S. Ruoff,Phys. Rev. Lett. 84, 5552 (2000).
J.P. Lu,Phys. Rev. Lett. 79, 1297 (1997).
Baughman et al., “Carbon Nanotube Actuators,” Science, May 21, 1999, vol. 284, pp. 1340-1344.
Fan et al., “Self-Oriented Regular Arrays of Carbon Nanotubes and Their Field Emission Properties,” Science, Jan. 22, 1999, vol. 283, pp. 512-514.
Forro et al., “Physical Properties of Multi-wall Nanotubes,” Carbon Nanotubes, Topics Appl. Phys., 2001, vol. 80, pp. 329-390.
Hata et al., “Water-Assisted Highly Efficient Synthesis of Impurity-Free Single-Walled Carbon Nanotubes,” Science, Nov. 19, 2004, vol. 306, pp. 1362-1364.
Iijima, Sumio, “Helical microtubules of graphitic carbon,” Nature, Nov. 7, 1991, vol. 354, pp. 56-58.
Kim et al., “Synthesis of Ultralong and High Percentage of Semiconducting Single-walled Carbon Nanotubes,” Nano Letters, 2002, vol. 2, No. 7, pp. 703-708.
Launois et al., “Structural Characterization of Nanotube Fibers by X-ray Scattering,” J. Nanosci. Nanotech., 2001, vol. 1, No. 2, pp. 125-128.
Li et al., “Tensile strength of single-walled carbon nanotubes directly measured from their macroscopic ropes,” Applied Physics Letters, Nov. 13, 2000, vol. 77, No. 20, pp. 3161-3163.
Pan et al., “Very long carbon nanotubes,” Nature, Aug. 13, 1998, vol. 394, pp. 631-632.
Rols et al., “Diffraction by finite-size crystalline bundles of single wall nanotubes,” Eur. Phys. J. B, 1999, vol. 10, pp. 263-270.
Thess et al., “Crystalline Ropes of Metallic Carbon Nanotubes,” Science, Jul. 26, 1996, vol. 273, pp. 483-487.
Zhu et al., “Direct Synthesis of Long Single-Walled Carbon Nanotube Strands,” Science, May 3, 2002, vol. 296, pp. 884-886.
Ajayan Pulickel M.
Wei Bingqing
Wu Dehai
Xu Cailu
Zhu Hongwei
Foley & Lardner LLP
Hendrickson Stuart
Rensselaer Polytechnic Institute
Tsinghua University
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