Direct synthesis by cationic polymerization of nitrogen-containi

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526126, 526147, 526189, 526190, 526194, 526217, 5262181, 526220, 526237, 526238, 5263487, 525245, 525248, 525249, 525319, 528408, 528409, 528411, 528416, C08F 404, C08F 414, C08F 1010

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050326538

ABSTRACT:
A method is provided for the direct synthesis of novel polymeric materials functionalized with desirable nitrogen-containing functional groups such as terminal azido, cyano, carbonylamino or thiocarbonylamino groups. Polymerization and functionalization occur in a substantially simultaneous manner. All necessary reactants for the functionalization are present when polymerization is initiated. The nitrogen-containing functional group is provided as a part of a molecule having a release moiety which is preferably resonance stabilized or a tertiary alkyl type and which acts to aid the nitrogen-containing species in functioning as a leaving group.

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