Direct sequestration of chloride ions

Compositions: coating or plastic – Coating or plastic compositions – Corrosion inhibiting coating composition

Reexamination Certificate

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C106S813000, C106S819000, C106S014210

Reexamination Certificate

active

07074263

ABSTRACT:
The present invention provides methods and compounds for the direct sequestration of chloride ions without requiring the addition of a source of anion such as nitrite or nitrate. A direct sequestration additive is introduced to fresh concrete or hardened concrete where the additive reacts with incoming chloride ions to form a low solubility, chloride-containing compound which captures or sequesters chloride ions. In a preferred embodiment, the chloride-containing compound comprises 3CaO.Fe(2-x)AlxO3.CaCl2.nH2O, where x ranges from about 0 to 1.4, and n ranges from about 8 to 24. The chloride ions may be provided in the form of deicing salt or sea water. Because chloride-containing compounds such as 3CaO.Fe(2-x)AlxO3.CaCl2.nH2O are formed directly without requiring the addition of a source of anion (e.g. nitrite or nitrate), the process is referred to as “direct sequestration.”

REFERENCES:
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patent: 4285733 (1981-08-01), Rosenberg et al.
patent: 5049412 (1991-09-01), Miller
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patent: 6610138 (2003-08-01), Brown
patent: 6755925 (2004-06-01), Brown
patent: 6810634 (2004-11-01), Brown
patent: 2004/0261341 (2004-12-01), Brown
“Inhibitors of corrosion of the reinforcement steel in concrete with addition of calcium chloride” Ratinov et al. Tr. Nauchn-lssled Inst Betona i Zhelezobetona (1961), No. 22, p. 40-53.
Taylor, Cement Chemistry, 1997, pp. 173-176.
American Concrete Institute, Committee 201 report: Guide to Durable Concrete, (no date available).
Taylor, Cement Chemistry, 1990, p. 28.

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